40 CFR 86.1323-2007 - Oxides of nitrogen analyzer calibration.

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§ 86.1323-2007 Oxides of nitrogen analyzer calibration.
This section describes the initial and periodic calibration of the chemiluminescent oxides of nitrogen analyzer.
(a) Prior to introduction into service and at least monthly thereafter, the chemiluminescent oxides of nitrogen analyzer must be checked for NO2 to NO converter efficiency. The Administrator may approve less frequent checks of the converter efficiency. Figure N84-9 is a reference for paragraphs (a) (1) through (11) of this section.
(1) Follow good engineering practices for instrument start-up and operation. Adjust the analyzer to optimize performance.
(2) Zero the oxides of nitrogen analyzer with zero-grade nitrogen.
(3) Connect the outlet of the NOX generator to the sample inlet of the oxides of nitrogen analyzer, which has been set to the most common operating range.
(4) Introduce into the NOX generator-analyzer system an NO-in-nitrogen (N2) mixture with an NO concentration equal to approximately 80 percent of the most common operating range. The NO2 content of the gas mixture shall be less than 5 percent of the NO concentration.
(5) With the oxides of nitrogen analyzer in the NO mode, record the concentration of NO indicated by the analyzer.
(6) Turn on the NOX generator O2 supply and adjust the O2 flow rate so that the NO indicated by the analyzer is about 10 percent less than indicated in paragraph (a)(5) of this section. Record the concentration of NO in this NO O2 mixture.
(7) Switch the NOX generator to the generation mode and adjust the generation rate so that the NO measured by the analyzer is 20 percent of that measured in paragraph (a)(5) of this section. There must be at least 10 percent unreacted NO at this point. Record the concentration of residual NO.
(8) Switch the oxides of nitrogen analyzer to the NOX mode and measure total NOX. Record this value.
(9) Switch off the NOX generator but maintain gas flow through the system. The oxides of nitrogen analyzer will indicate the NOX in the NO O2 mixture. Record this value.
(10) Turn off the NOX generator O2 supply. The analyzer will now indicate the NOX in the original NO-in-N2 mixture. This value should be no more than 5 percent above the value indicated in paragraph (a)(4) of this section.
(11) Calculate the efficiency of the NOX converter by substituting the concentrations obtained into the following equation:
Where:
a = concentration obtained in paragraph (a)(8) of this section,
b = concentration obtained in paragraph (a)(9) of this section,
c = concentration obtained in paragraph (a)(6) of this section,
d = concentration obtained in paragraph (a)(7) of this section.
(12) If converter efficiency is not greater than 90 percent, repair the analyzer. The repaired analyzer must achieve a converter efficiency greater than 90 percent before the analyzer may be used.
(b) Accuracy. The accuracy at the minimum limit of the NOX analyzer is defined in § 86.1338-2007. In general the analyzer's minimum limit shall be the lowest concentration within a given range, in which it has an accuracy of ±2 percent of point.
(c) Initial and periodic calibration. Prior to its introduction into service and monthly thereafter, the chemiluminescent oxides of nitrogen analyzer shall be calibrated on all normally used instrument ranges. Use the same flow rate as when analyzing samples. Proceed as follows:
(1) Adjust analyzer to optimize performance.
(2) Zero the oxides of nitrogen analyzer with zero-grade nitrogen (N2).
(3)
(i) Calibrate all operating ranges with a minimum of 9 NO-in-N2 calibration gases (e.g., 10, 20, 30, 40, 50, 60, 70, 80, and 90 percent of that range) and one zero-grade N2 gas. Sound engineering judgment shall dictate appropriate spacing and weighting of the calibration points.
(ii) For each range calibrated, if all deviations from a least-squares best-fit straight line are within ±2 percent of the value at each non-zero data point and within ±0.3 percent of full scale on the zero data point, then concentration values may be calculated using the linear calibration equation for that range. If the specified deviations are exceeded for ranges that have a minimum limit of 1 ppm or greater, then the best-fit non-linear equation that represents the data within these deviations may be used to determine concentration values. For ranges that have a minimum limit less than 1 ppm, only a linear or second order non-linear equation that represents the data within these deviations, may be used to determine concentration values.
(d) Chemiluminescent NO X analyzer interference check (i.e., quench check).Prior to its introduction into service and at least once per year thereafter, the quench check described in this section shall be performed on CLD NOX analyzers. CO2 and water vapor interfere with the response of a CLD by collisional quenching. The combined quench effect at their highest expected concentrations shall not exceed 2 percent.
(1) CO 2 quench check procedure. (i) For the procedure described in this paragraph, variations are acceptable provided that they produce equivalent %CO2quench results. Connect a pressure-regulated CO2 span gas to one of the inlets of a three-way valve. Its CO2 concentration should be approximately twice the maximum CO2 concentration expected during testing. The valve must be leak-free, and its wetted parts must be made of a stainless steel or other inert material. Connect a pressure-regulated zero-grade N2 gas to the other inlet of the three-way valve. Connect the single outlet of the valve to the balance-gas port of a properly operating gas divider. Connect a pressure-regulated NO span gas, which has approximately twice the typical NO concentration expected during testing, to the span-port of the gas divider. Configure the gas divider such that nearly equal amounts of the span gas and balance gas are blended with each other. Viscosity corrections shall be applied appropriately to ensure correct mass flow determinations.
(ii) With the CO2 flowing to the balance port and the NO flowing to the span port, measure a stable CO2 concentration from the gas divider's outlet with a properly calibrated NDIR analyzer. Record this concentration in percent (%); this is “%CO2”. This value will be used in the water vapor quench check calculations that are detailed in the following section. After the %CO2 measurement, measure the NO concentration at the gas divider outlet with the CLD analyzer in the NO mode. Record this concentration in ppm; this is “NOCO2”. Then switch the three-way valve such that 100 percent N2 flows to the balance port inlet. Monitor the CO2 concentration of the gas divider's outlet until its concentration stabilizes at zero. Then measure the stable NO concentration from the gas divider's outlet. Record this value in ppm; this is “NON2”. Calculate %CO2quench as follows:
%CO2quench = (1.00−(NOCO2/NON2)) × 100
(2) Water vapor quench check procedure:
(i) For all dry CLD analyzers it must be demonstrated that for the highest expected water vapor concentration (i.e., “%H2Oexp” as calculated later in this section), the water removal technique maintains CLD humidity at less than or equal to 5 gwater/kgdry air (or about 0.008 percent H2O), which is 100% RH at 3.9 °C and 101.3 kPa. This humidity specification is also equivalent to about 25% RH at 25 °C and 101.3 kPa. This may be demonstrated by measuring the temperature at the outlet of a thermal dehumidifier, or by measuring humidity at a point just upstream of the CLD. Humidity of the CLD exhaust might also be measured as long as the only flow into the CLD is the flow out of the dehumidifier.
(ii) For all “wet” CLD analyzers the following water vapor quench check procedure shall be followed. Measure an NO span gas, which has 90% to 100% of the typical NO expected during testing, using the CLD in the NO mode. Record this concentration in ppm; this is “NOdry”. Then bubble the same NO span gas through distilled water in a sealed vessel at 25 °C ±10 °C. This temperature specification imposed to ensure that the H2Ovol calculation (refer to (iii) of this section) returns an accurate result. To prevent subsequent condensation, this temperature must also be less than any temperature that the wetted sample will experience between the sealed vessel's outlet and the CLD. Record the vessel's water temperature in °C; this is “Tsat”. Record the vessel's absolute pressure in kPa; this is “Psat”. Measure the wetted span gas with the CLD, and record this value in ppm; this is “NOwet”.
(iii) Calculations for water quench must consider dilution of the NO span gas with water vapor and scaling of the water vapor concentration to that expected during testing.
(A) Calculate the volume fraction of water vapor in the wetted span gas, as H2Ovol = (exp(3.69−(81.28/Tsat)) 1.61)/Psat. This calculation approximates some of the thermodynamic properties of water based on the “1995 Formulation for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use”, issued by The International Association for the Properties of Water and Steam (IAPWS). However, this approximation should only be used as prescribed in this section because it is an exponential fit that is accurate for data at 25 °C ±10 °C. Then, assuming a diesel fuel atomic hydrogen to carbon ratio of 1.8, and an intake and dilution air humidity of 75 grains (10.71 gwater/kgdry air or 54.13 percent RH at 25 °C and 101.3 kPa),
(B) Calculate the maximum percent water vapor expected during testing; as %H2Oexp = (0.90 × %CO2) 1.69. %CO2 is the value measured during the %CO2 quench check.
(C) Calculate the expected wet concentration of NO in ppm; as NOexp = NOdry × (1.00−H2Ovol)
(iv) Calculate the percent water vapor quench as:
%H2Oquench = ((NOexp−NOwet)/NOexp) × (%H2Oexp/H2Ovol)
(3) Add the %CO2quench and the %H2Oquench values. Their sum may not exceed the limit set in paragraph (d). If their sum is greater than this limit, then the CLD instrument may not be used to perform testing unless it is repaired. The analyzer must be shown to pass this quench check after the repair before it may be used for testing.
[66 FR 5182, Jan. 18, 2001]

Title 40 published on 2013-07-01

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  • 2014-08-08; vol. 79 # 153 - Friday, August 8, 2014
    1. 79 FR 46356 - Emergency Vehicle Rule—SCR Maintenance and Regulatory Flexibility for Nonroad Equipment
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      ENVIRONMENTAL PROTECTION AGENCY
      Final rule.
      This rule is effective on September 8, 2014.
      40 CFR Parts 86 and 1039

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United States Code
U.S. Code: Title 42 - THE PUBLIC HEALTH AND WELFARE

§ 7401 - Congressional findings and declaration of purpose

§ 7402 - Cooperative activities

§ 7403 - Research, investigation, training, and other activities

§ 7404 - Research relating to fuels and vehicles

§ 7405 - Grants for support of air pollution planning and control programs

§ 7406 - Interstate air quality agencies; program cost limitations

§ 7407 - Air quality control regions

§ 7408 - Air quality criteria and control techniques

§ 7409 - National primary and secondary ambient air quality standards

§ 7410 - State implementation plans for national primary and secondary ambient air quality standards

§ 7411 - Standards of performance for new stationary sources

§ 7412 - Hazardous air pollutants

§ 7413 - Federal enforcement

§ 7414 - Recordkeeping, inspections, monitoring, and entry

§ 7415 - International air pollution

§ 7416 - Retention of State authority

§ 7417 - Advisory committees

§ 7418 - Control of pollution from Federal facilities

§ 7419 - Primary nonferrous smelter orders

§ 7420 - Noncompliance penalty

§ 7421 - Consultation

§ 7422 - Listing of certain unregulated pollutants

§ 7423 - Stack heights

§ 7424 - Assurance of adequacy of State plans

§ 7425 - Measures to prevent economic disruption or unemployment

§ 7426 - Interstate pollution abatement

§ 7427 - Public notification

§ 7428 - State boards

§ 7429 - Solid waste combustion

§ 7430 - Emission factors

§ 7431 - Land use authority

§ 7450 to 7459 - Repealed.

§ 7470 - Congressional declaration of purpose

§ 7471 - Plan requirements

§ 7472 - Initial classifications

§ 7473 - Increments and ceilings

§ 7474 - Area redesignation

§ 7475 - Preconstruction requirements

§ 7476 - Other pollutants

§ 7477 - Enforcement

§ 7478 - Period before plan approval

§ 7479 - Definitions

§ 7491 - Visibility protection for Federal class I areas

§ 7492 - Visibility

§ 7501 - Definitions

§ 7502 - Nonattainment plan provisions in general

§ 7503 - Permit requirements

§ 7504 - Planning procedures

§ 7505 - Environmental Protection Agency grants

§ 7505a - Maintenance plans

§ 7506 - Limitations on certain Federal assistance

§ 7506a - Interstate transport commissions

§ 7507 - New motor vehicle emission standards in nonattainment areas

§ 7508 - Guidance documents

§ 7509 - Sanctions and consequences of failure to attain

§ 7509a - International border areas

§ 7511 - Classifications and attainment dates

§ 7511a - Plan submissions and requirements

§ 7511b - Federal ozone measures

§ 7511c - Control of interstate ozone air pollution

§ 7511d - Enforcement for Severe and Extreme ozone nonattainment areas for failure to attain

§ 7511e - Transitional areas

§ 7511f - NO

§ 7512 - Classification and attainment dates

§ 7512a - Plan submissions and requirements

§ 7513 - Classifications and attainment dates

§ 7513a - Plan provisions and schedules for plan submissions

§ 7513b - Issuance of RACM and BACM guidance

§ 7514 - Plan submission deadlines

§ 7514a - Attainment dates

§ 7515 - General savings clause

§ 7521 - Emission standards for new motor vehicles or new motor vehicle engines

§ 7522 - Prohibited acts

§ 7523 - Actions to restrain violations

§ 7524 - Civil penalties

§ 7525 - Motor vehicle and motor vehicle engine compliance testing and certification

§ 7541 - Compliance by vehicles and engines in actual use

§ 7542 - Information collection

§ 7543 - State standards

§ 7544 - State grants

§ 7545 - Regulation of fuels

§ 7546 - Renewable fuel

§ 7547 - Nonroad engines and vehicles

§ 7548 - Study of particulate emissions from motor vehicles

§ 7549 - High altitude performance adjustments

§ 7550 - Definitions

§ 7551 - Omitted

§ 7552 - Motor vehicle compliance program fees

§ 7553 - Prohibition on production of engines requiring leaded gasoline

§ 7554 - Urban bus standards

§ 7571 - Establishment of standards

§ 7572 - Enforcement of standards

§ 7573 - State standards and controls

§ 7574 - Definitions

§ 7581 - Definitions

§ 7582 - Requirements applicable to clean-fuel vehicles

§ 7583 - Standards for light-duty clean-fuel vehicles

§ 7584 - Administration and enforcement as per California standards

§ 7585 - Standards for heavy-duty clean-fuel vehicles (GVWR above 8,500 up to 26,000 lbs.)

§ 7586 - Centrally fueled fleets

§ 7587 - Vehicle conversions

§ 7588 - Federal agency fleets

§ 7589 - California pilot test program

§ 7590 - General provisions

§ 7601 - Administration

§ 7602 - Definitions

§ 7603 - Emergency powers

§ 7604 - Citizen suits

§ 7605 - Representation in litigation

§ 7606 - Federal procurement

§ 7607 - Administrative proceedings and judicial review

§ 7608 - Mandatory licensing

§ 7609 - Policy review

§ 7610 - Other authority

§ 7611 - Records and audit

§ 7612 - Economic impact analyses

§ 7613 - Repealed.

§ 7614 - Labor standards

§ 7615 - Separability

§ 7616 - Sewage treatment grants

§ 7617 - Economic impact assessment

§ 7618 - Repealed.

§ 7619 - Air quality monitoring

§ 7620 - Standardized air quality modeling

§ 7621 - Employment effects

§ 7622 - Employee protection

§ 7623 - Repealed.

§ 7624 - Cost of vapor recovery equipment

§ 7625 - Vapor recovery for small business marketers of petroleum products

42 U.S. Code § 7450 to 7459 - Repealed.

§ 7625a - Statutory construction

§ 7626 - Authorization of appropriations

§ 7627 - Air pollution from Outer Continental Shelf activities

§ 7628 - Demonstration grant program for local governments

§ 7641 - Noise abatement

§ 7642 - Authorization of appropriations

§ 7651 - Findings and purposes

§ 7651a - Definitions

§ 7651b - Sulfur dioxide allowance program for existing and new units

§ 7651c - Phase I sulfur dioxide requirements

§ 7651d - Phase II sulfur dioxide requirements

§ 7651e - Allowances for States with emissions rates at or below 0.80 lbs/mmBtu

§ 7651f - Nitrogen oxides emission reduction program

§ 7651g - Permits and compliance plans

§ 7651h - Repowered sources

§ 7651i - Election for additional sources

§ 7651j - Excess emissions penalty

§ 7651k - Monitoring, reporting, and recordkeeping requirements

42 U.S. Code § -

§ 7651m - Enforcement

§ 7651n - Clean coal technology regulatory incentives

42 U.S. Code § -

§ 7661 - Definitions

§ 7661a - Permit programs

§ 7661b - Permit applications

§ 7661c - Permit requirements and conditions

§ 7661d - Notification to Administrator and contiguous States

§ 7661e - Other authorities

§ 7661f - Small business stationary source technical and environmental compliance assistance program

§ 7671 - Definitions

§ 7671a - Listing of class I and class II substances

§ 7671b - Monitoring and reporting requirements

§ 7671c - Phase-out of production and consumption of class I substances

§ 7671d - Phase-out of production and consumption of class II substances

§ 7671e - Accelerated schedule

§ 7671f - Exchange authority

§ 7671g - National recycling and emission reduction program

§ 7671h - Servicing of motor vehicle air conditioners

§ 7671i - Nonessential products containing chlorofluorocarbons

§ 7671j - Labeling

§ 7671k - Safe alternatives policy

42 U.S. Code § -

§ 7671m - Relationship to other laws

§ 7671n - Authority of Administrator

42 U.S. Code § -

§ 7671p - International cooperation

§ 7671q - Miscellaneous provisions

Title 40 published on 2013-07-01

The following are ALL rules, proposed rules, and notices (chronologically) published in the Federal Register relating to 40 CFR 86 after this date.

  • 2014-08-08; vol. 79 # 153 - Friday, August 8, 2014
    1. 79 FR 46356 - Emergency Vehicle Rule—SCR Maintenance and Regulatory Flexibility for Nonroad Equipment
      GPO FDSys XML | Text
      ENVIRONMENTAL PROTECTION AGENCY
      Final rule.
      This rule is effective on September 8, 2014.
      40 CFR Parts 86 and 1039