49 CFR § 173.4a - Excepted quantities.
(a) Excepted quantities of materials, other than articles (e.g., aerosols), are not subject to requirements of this subchapter except for:
(b) Authorized materials. Only materials authorized for transport aboard passenger aircraft and appropriately classed within one of the following hazard classes or divisions may be transported in accordance with this section:
(2) Class 3 materials;
(3) Class 4 (PG II and III) materials except for self-reactive materials;
(4) Division 5.1 (PG II and III);
(5) Division 5.2 materials only when contained in a chemical kit, first aid kit or a polyester resin kit;
(7) Class 7, Radioactive material in excepted packages
(8) Class 8 (PG II and III), except for UN2803 (Gallium) and UN2809 (Mercury); and
(i) 1 g (0.04 ounce) for solids; or
(ii) 1 mL (0.03 ounce) for liquids;
(3) For gases a water capacity of 30 mL (1.8 cubic inches) or less.
(d) Outer packaging aggregate quantity limits. The maximum aggregate quantity of hazardous material contained in each outer packaging must not exceed the limits provided in the following paragraphs. For outer packagings containing more than one hazardous material, the aggregate quantity of hazardous material must not exceed the lowest permitted maximum aggregate quantity. The limits are as follows:
(2) For Division 2.2 material, 1 L (61 cubic inches); or
(e) Packaging materials. Packagings used for the transport of excepted quantities must meet the following:
(1) Each inner receptacle must be constructed of plastic, or of glass, porcelain, stoneware, earthenware or metal. When used for liquid hazardous materials, plastic inner packagings must have a thickness of not less than 0.2 mm (0.008 inch).
(2) Each inner packaging with a removable closure must have its closure held securely in place with wire, tape or other positive means. Each inner receptacle having a neck with molded screw threads must have a leak proof, threaded type cap. The closure must not react chemically with the material.
(3) Each inner packaging must be securely packed in an intermediate packaging with cushioning material in such a way that, under normal conditions of transport, it cannot break, be punctured or leak its contents. The completed package as prepared for transport must completely contain the contents in case of breakage or leakage, regardless of package orientation. For liquid hazardous materials, the intermediate or outer packaging must contain sufficient absorbent material that:
(i) Will absorb the entire contents of the inner packaging.
(ii) Will not react dangerously with the material or reduce the integrity or function of the packaging materials.
(iii) When placed in the intermediate packaging, the absorbent material may be the cushioning material.
(6) Each package must be of such a size that there is adequate space to apply all necessary markings.
(f) Package tests. The completed package as prepared for transport, with inner packagings filled to not less than 95% of their capacity for solids or 98% for liquids, must be capable of withstanding, as demonstrated by testing which is appropriately documented, without breakage or leakage of any inner packaging and without significant reduction in effectiveness:
(1) Drops onto a solid unyielding surface from a height of 1.8 m (5.9 feet):
(i) Where the sample is in the shape of a box, it must be dropped in each of the following orientations:
(A) One drop flat on the bottom;
(B) One drop flat on the top;
(C) One drop flat on the longest side;
(D) One drop flat on the shortest side; and
(E) One drop on a corner at the junction of three intersecting edges.
(ii) Where the sample is in the shape of a drum, it must be dropped in each of the following orientations:
(A) One drop diagonally on the top chime, with the center of gravity directly above the point of impact;
(B) One drop diagonally on the base chime; and
(C) One drop flat on the side.
(2) A compressive load as specified in § 178.606(c) of this subchapter. Each of the tests in this paragraph (f) of this section may be performed on a different but identical package; that is, all tests need not be performed on the same package.
(g) Marking. Excepted quantities of hazardous materials packaged, marked, and otherwise offered and transported in accordance with this section must be durably and legibly marked with the following marking:
(1) The “*” must be replaced by the primary hazard class, or when assigned, the division of each of the hazardous materials contained in the package. The “**” must be replaced by the name of the shipper or consignee if not shown elsewhere on the package.
(2) The marking must be durable and clearly visible and in the form of a square. The hatching must be of the same color, black or red on white or a suitable contrasting background. The minimum dimensions must not be less than 100 mm (3.9 inches) by 100 mm (3.9 inches) as measured from the outside of the hatching forming the border. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
(i) Transitional exception - A marking in conformance with the requirements of this paragraph in effect on December 31, 2014, may continue to be used until December 31, 2016.
(ii) For domestic transportation, a packaging marked prior to January 1, 2017 and in conformance with the requirements of this paragraph in effect on December 31, 2014, may continue in service until the end of its useful life.
(3) When packages of excepted quantities are contained in an overpack, and the package marking required by this section is not visible inside the overpack, the excepted quantities marking must also be placed on the overpack. Additionally, an overpack containing packages of excepted quantities is not required to be marked with the word “OVERPACK.”
(1) For transportation by highway or rail, no shipping paper is required.
(2) For transport by air, a shipping paper is not required, except that, if a document such as an air waybill accompanies a shipment, the document must include the statement “Dangerous Goods in Excepted Quantities” and indicate the number of packages.