Ala. Admin. Code r. 335-14-6-.13 - Land Treatment

(1) Applicability. The requirements of 335-14-6-.13 apply to owners and operators of hazardous waste land treatment facilities, except as 335-14-6-.01(1) provides otherwise.

(2) [Reserved].

(3) General operating requirements.

(a) Hazardous waste must not be placed in or on a land treatment facility unless the waste can be made less hazardous or nonhazardous by degradation, transformation or immobilization processes occurring in or on the soil.

(b) The owner or operator must design, construct, operate, and maintain a run-on control system capable of preventing flow onto the active portions of the facility during peak discharge from at least a 25-year storm.

(c) The owner or operator must design, construct, operate, and maintain a run-off management system capable of collecting and controlling a water volume at least equivalent to a 24-hour, 25 year storm.

(d) Collection and holding facilities (e.g., tanks or basins) associated with run-on and run-off control systems must be emptied or otherwise managed expeditiously after storms to maintain design capacity of the system.

(e) If the treatment zone contains particulate matter which may be subject to wind dispersal, the owner or operator must manage the unit to control wind dispersal.

(4) Waste analysis. In addition to the waste analyses required by 335-14-6-.02(4), before placing a hazardous waste in or on a land treatment facility, the owner or operator must:

(a) Determine the concentrations in the waste of any substances which equal or exceed the maximum concentrations contained in Table 1 of 335-14-2-.03(5) that cause a waste to exhibit the Characteristic of toxicity;

(b) For any waste listed in Rule 335-14-2-.04, determine the concentrations in the waste of each of the following constituents: arsenic, cadmium, lead, and mercury, unless the owner or operator has written, documented data that show that the constituent is not present;

(c) For any waste listed in Rule 335-14-2-.04, determine the concentrations of any substances which caused the waste to be listed as a hazardous waste; and

(d) If food chain crops are grown, determine the concentrations in the waste of each of the following constituents: arsenic, cadmium, lead, and mercury, unless the owner or operator has written, documented data that show that the constituent is not present.

(5) [Reserved].

(6) [Reserved].

(7) Food chain crops.

(a) An owner or operator of a hazardous waste land treatment facility on which food chain crops are being grown, or have been grown and will be grown in the future, must notify the Department within 60 days after the effective date of 335-14-6.

(b)

1. Food chain crops must not be grown on the treated area of a hazardous waste land treatment facility unless the owner or operator can demonstrate, based on field testing, that any arsenic, lead, mercury, or other constituents identified under 335-14-6-.13(4)(b):

(i) Will not be transferred to the food portion of the crop by plant uptake or direct contact, and will not otherwise be ingested by food chain animals (e.g., by grazing); or,

(ii) Will not occur in greater concentrations in the crops grown on the land treatment facility than in the same crops grown on untreated soils under similar conditions in the same region.

2. The information necessary to make the demonstration required by 335-14-6 -.13(7)(b)1. must be kept at the facility and must, at a minimum:

(i) Be based on tests for the specific waste and application rates being used at the facility; and

(ii) Include descriptions of crop and soil characteristics, sample selection criteria, sample size determination, analytical methods, and statistical procedures.

(c) Food chain crops must not be grown on a land treatment facility receiving waste that contains cadmium unless all requirements of 335-14-6-.13(7)(c)1.(i) through (iii) or all requirements of 335-14-6-.13(7)(c)2.(i) through (iv) are met.

1.

(i) The pH of the waste and soil mixture is 6.5 or greater at the time of each waste application, except for waste containing cadmium at concentrations of 2 mg/kg (dry weight) or less;

(ii) The annual application of cadmium from waste does not exceed 0.5 kilograms per hectare (kg/ha) on land used for production of tobacco, leafy vegetables, or root crops grown for human consumption. For other food chain crops, the annual cadmium application rate does not exceed:

Time period Annual Cd application rate (kg/ha)

Present to Dec. 31, 1986.................. 1.25

Beginning Jan. 1, 1987.................... 0.5

(iii) The cumulative application of cadmium from waste does not exceed the levels in either 335-14-6 -.13(7)(c)1.(iii)(I) or (II).

(I)

See Table at http://www.alabamaadministrativecode.state.al.us/docs/adem/MWd14ADEM6.pdf

(II) For soils with a background pH of less than 6.5, the cumulative cadmium application rate does not exceed the levels below: Provided, that the pH of the waste and soil mixture is adjusted to and maintained at 6.5 or greater whenever food chain crops are grown.

Soil cation exchange capacity (meg/lOOg) Maximum cumulative application (kg/ha)

Less than 5 5

5 to 15 10

Greater than 15 20

2.

(i) The only food chain crop produced is animal feed.

(ii) The pH of the waste and soil mixture is 6.5 or greater at the time of the waste application or at the time the crop is planted, whichever occurs later, and this pH level is maintained whenever food chain crops are grown.

(iii) There is a facility operating plan which demonstrates how the animal feed will be distributed to preclude ingestion by humans. The facility operating plan describes the measures to be taken to safeguard against possible health hazards from cadmium entering the food chain, which may result from alternative land uses.

(iv) Future property owners are notified by a stipulation in the land record or property deed which states that the property has received waste at high cadmium application rates and that food chain crops must not be grown except in compliance with 335-14-6 -.13(7)(c)2.

(8) [Reserved].

(9) Unsaturated zone (zone of aeration monitoring).

(a) The owner or operator must have in writing, and must implement, an unsaturated zone monitoring plan which is designed to:

1. Detect the vertical migration of hazardous waste and hazardous waste constituents under the active portion of the land treatment facility, and

2. Provide information on the background concentrations of the hazardous waste and hazardous waste constituents in similar but untreated soils nearby; this background monitoring must be conducted before or in conjunction with the monitoring required under 335-14-6 -.13(9)(a)1.

(b) The unsaturated zone monitoring plan must include, at a minimum:

1. Soil monitoring using soil cores, and

2. Soil-pore water monitoring using devices such as lysimeters.

(c) To comply with 335-14-6-.13(9)(a)1., the owner or operator must demonstrate in his unsaturated zone monitoring plan that:

1. The depth at which soil and soil-pore water samples are to be taken is below the depth to which the waste is incorporated into the soil;

2. The number of soil and soil-pore water samples to be taken is based on the variability of:

(i) The hazardous waste constituents (as identified in 335-14-6-.13(4)(a) and (4)(b) ) in the waste and in the soil; and

(ii) The soil type(s); and

3. The frequency and timing of soil and soil-pore water sampling is based on the frequency, time, and rate of waste application, proximity to groundwater, and soil permeability.

(d) The owner or operator must analyze the soil and soil-pore water samples for the hazardous waste constituents that were found in the waste during the waste analysis under 335-14-6-.13(4)(a) and (4)(b).

(10) Recordkeeping. The owner or operator must include hazardous waste application dates and rates in the operating record required under 335-14-6-.05(4).

(11) Closure and post-closure.

(a) In the closure plan under 335-14-6-.07(3) and the post-closure plan under 335-14-6-.07(9), the owner or operator must address the following objectives and indicate how they will be achieved:

1. Control of the migration of hazardous waste and hazardous waste constituents from the treated area into the groundwater;

2. Control of the release of contaminated run-off from the facility into surface water;

3. Control of the release of airborne particulate contaminants caused by wind erosion; and

4. Compliance with 335-14-6-.13(7) concerning the growth of food-chain crops.

(b) The owner or operator must consider at least the following factors in addressing the closure and post-closure care objectives of 335-14-6-.13(9)(a):

1. Type and amount of hazardous waste and hazardous waste constituents applied to the land treatment facility;

2. The mobility and the expected rate of migration of the hazardous waste and hazardous waste constituents;

3. Site location, topography, and surrounding land use, with respect to the potential effects of pollutant migration (e.g., proximity to groundwater, surface water, and drinking water sources);

4. Climate, including amount, frequency, and pH of precipitation;

5. Geological and soil profiles and surface and subsurface hydrology of the site, and soil characteristics, including cation exchange capacity, total organic carbon, and pH;

6. Unsaturated zone monitoring information obtained under 335-14-6-.13(9); and

7. Type, concentration, and depth of migration of hazardous waste constituents in the soil as compared to their background concentrations.

(c) The owner or operator must consider at least the following methods in addressing the closure and post-closure care objectives of 335-14-6-.13(9)(a):

1. Removal of contaminated soils;

2. Placement of a final cover, considering:

(i) Functions of the cover (e.g., infiltration control and wind erosion control); and

(ii) Characteristics of the cover, including material, final surface contours, thickness, porosity and permeability, slope, length of run of slope, and type of vegetation on the cover; and

3. Monitoring of groundwater.

(d) In addition to the requirements of Rule 335-14-6-.07, during the closure period the owner or operator of a land treatment facility must:

1. Continue unsaturated zone monitoring in a manner and frequency specified in the closure plan, except that soil pore liquid monitoring may be terminated 90 days after the last application of waste to the treatment zone;

2. Maintain the run-on control system required under 335-14-6-.13(3)(b);

3. Maintain the run-off management system required under 335-14-6-.13(3)(c); and

4. Control wind dispersal or particulate matter which may be subject to wind dispersal.

(e) For the purpose of complying with 335-14-6-.07(6), when closure is completed the owner or operator may submit to the Department certification both by the owner or operator and by an independent qualified soil scientist, in lieu of an independent registered professional engineer, that the facility has been closed in accordance with the specifications in the approved closure plan.

(f) In addition to the requirements of 335-14-6-.07(8), during the post-closure care period the owner or operator of a land treatment unit must:

1. Continue soil-core monitoring by collecting and analyzing samples in a manner and frequency specified in the post-closure plan;

2. Restrict access to the unit as appropriate for its post-closure use;

3. Assure that growth of food chain crops complies with 335-14-6-.13(7); and

4. Control wind dispersal of hazardous waste.

(12) Special requirement for ignitable or reactive waste. The owner or operator must not apply ignitable or reactive waste to the treatment zone unless the waste and treatment zone meet all applicable requirements of Chapter 335-14-9, and:

(a) The waste is immediately incorporated into the soil so that:

1. The resulting waste, mixture, or dissolution of material no longer meets the definition of ignitable or reactive waste under 335-14-2-.03(2) or (4); and

2.335-14-6-.02(8)(b) is complied with; or

(b) The waste is managed in such a way that it is protected from any material or conditions which may cause it to ignite or react.

(13) Special requirements for incompatible wastes. Incompatible wastes, or incompatible wastes and material (see 335-14-6 - Appendix V for examples), must not be placed in the same land treatment area, unless 335-14-6-.02(8)(b) is complied with.

Authors: Stephen C. Maurer, C. Edwin Johnston

Notes

Ala. Admin. Code r. 335-14-6-.13

November 19, 1980. Amended: April 9, 1986; September 29, 1986; August 24, 1989; December 6, 1990. Amended: Filed November 30, 1994; effective January 5, 1995. Amended: Filed March 9, 2001; effective April 13, 2001.

Statutory Authority: Code of Ala. 1975, §§ 22-30-11, 22-30-16.