Leachate sampling and analysis.
Throughout the operation, closure, and post-closure care, the owner or operator
shall do the following:
(1) Sample and test
leachate in accordance with the following unless the facility was licensed and
operating on December 22, 2005, and was not required to have a leachate
monitoring system on that date. For the purposes of this rule, a "leachate
monitoring system" is any leachate collection system that includes sump risers
or other access that can be used for collecting samples of leachate.
(a) Sampling frequency.
(i)
An
The owner or
operator shall sample leachate at the facility at least annually.
(ii) If the owner or operator recirculates
leachate after the effective date of this
rule
January 1, 2013, the owner or
operator shall sample leachate at the facility at least quarterly.
(b) Sampling locations.
(i) At least annually
an
the owner
or operator shall obtain at least one representative leachate sample from a
minimum of one sump collecting leachate from areas of the facility containing
disposed material. Within every five year period, an
the owner or
operator shall obtain at least one representative leachate sample from each
sump collecting leachate from areas of the facility containing disposed
material.
(ii) At least quarterly
an
the owner
or operator that has recirculated leachate through a facility after
the effective date of this rule
January 1, 2013 shall obtain at least one
representative leachate sample from each sump capable of collecting leachate
from such areas of the facility receiving the recirculated leachate.
[Comment: The director or health
commissioner of the licensing authority may utilize authority under
section 3714.04 of the Revised Code to
specify different sampling locations and frequencies than required by this rule
as deemed appropriate.]
(c) Field analysis. During each leachate
sampling event, an
the owner or operator shall measure the pH, specific
conductance, temperature, and turbidity for each sump from which a sample is
taken.
(d) Laboratory analysis.
(i)
An
The owner or
operator shall analyze each leachate sample for the parameters listed in rule
3745-400-21 of the
Administrative Code.
(ii) The
practical quantitation limit (PQL) used for laboratory analysis shall be the
following:
(a) The lowest concentration level
that can be reliably achieved during routine laboratory operating conditions
that are reasonably available for the analytical method chosen by the owner or
operator, unless paragraph (A)(1)(d)(iii) of this rule applies.
(b) Lower than the primary drinking water
standard for the parameter included in Chapter 3745-81 of the Administrative
Code, if one exists, and the secondary drinking water standard for the
parameter included in Chapter 3745-82 of the Administrative Code, if one
exists, unless paragraph (A)(1) (d)(ii)
(A)(1)(d)(iii) of this rule applies.
(iii) If the PQL does not comply
with paragraph (A)(1)(d)(ii) of this rule
,
then an
the owner or operator shall do one of the following:
(a) Choose alternative sampling or analytical
procedures or choose an alternative analytical method that will result in a PQL
that complies with paragraph (A)(1)(d)(ii) of this rule and reanalyze the
sample or resample.
(b) Identify
and report interferences that prevent the use of a PQL meeting the requirements
of paragraph (A)(1)(d)(ii) of this rule and provide a written justification in
the leachate report why the use of another procedure or method in accordance
with paragraph (A)(1)(d)(iii)(a) of this rule is impractical.
(c) Conclude that the parameter has been
detected in leachate for the purpose of conducting ground water detection
monitoring in accordance with paragraph (B) of this rule.
(e) Submitting the sampling and
analysis results.
An
The owner or operator shall submit to the director and
approved board of
the health
commissioner of the
licensing authority the following information not later than seventy-five
days after each leachate sampling event:
(i)
The results of the field analysis required by paragraph (A)(1)(c) of this
rule.
(ii) The results of the
laboratory analysis of the parameters listed in rule
3745-400-21 of the
Administrative Code in the same order as listed in rule
3745-400-21 of the
Administrative Code.
(iii)
Identification of the leachate parameters required by paragraph (B) of this
rule to be monitored in ground water.
(iv) Quality control data used by the
laboratory to determine whether the analysis results are accurate.
(v) The method detection limits, PQLs, and
analysis methods used.
(vi) Forms
in the leachate sampling and analysis plan that were completed during leachate
sampling and analysis.
(2) Develop and comply with a leachate
sampling and analysis plan that contains the following:
(a) A description of the equipment,
procedures, and techniques to be used to sample and analyze leachate in
accordance with this rule. Sample collection, preservation, and handling
methods described in the plan shall provide for collection of representative
samples of leachate.
[Comment: An
The owner or operator is not required to include
references to specific laboratory analysis methods, specific method detection
limits, or specific practical quantitation limits in the leachate sampling and
analysis plan.]
(b) Blank
forms to be used to record the information obtained during leachate sampling
and analysis including at a minimum the following types of forms:
(i) Forms for recording field analysis
results and conditions encountered at the facility during a sampling
event.
(ii) Forms for recording the
chain of custody of leachate samples.