Ohio Admin. Code 3745-51-734 - Test methods and procedures - process vents
(A)
Each
remanufacturer or other person who stores or treats the hazardous secondary
material subject to rules
3745-51-730 to
3745-51-735 of the
Administrative Code shall comply with the test methods and procedural
requirements provided in this rule.
(B)
When a
closed-vent system is tested for compliance with no detectable emissions, as
required in paragraph (L) of rule
3745-51-733 of the
Administrative Code, the test shall comply with the following
requirements:
(1)
Monitoring shall comply with reference method 21 in 40
CFR Part 60 .
(2)
The detection instrument shall meet the performance
criteria of reference method 21.
(3)
The instrument
shall be calibrated before use on each day of the instrument's use by the
procedures specified in reference method 21.
(4)
Calibration gases
shall be:
(a)
Zero air (less than ten parts per million (ppm) of
hydrocarbon in air).
(b)
A mixture of methane or n-hexane and air at a
concentration of approximately, but less than, ten thousand ppm methane or
n-hexane.
(5)
The background level shall be determined as provided in
reference method 21.
(6)
The instrument probe shall be traversed around all
potential leak interfaces as close to the interface as possible as described in
reference method 21.
(7)
The arithmetic difference between the maximum
concentration indicated by the instrument and the background level is compared
with five hundred ppm for determining compliance.
(C)
Performance tests
to determine compliance with paragraph (A) of rule
3745-51-732 of the
Administrative Code and with the total organic compound concentration limit of
paragraph (C) of rule
3745-51-733 of the
Administrative Code shall comply with the following:
(1)
Performance tests
to determine total organic compound concentrations and mass flow rates entering
and exiting control devices shall be conducted and data reduced in accordance
with the following reference methods and calculation procedures:
(a)
Method 2 in 40
CFR Part 60 for velocity and volumetric flow rate.
(b)
Method 18 or
method 25A in 40 CFR Part 60, appendix A, for organic content. If method 25A is
used, the organic hazardous air pollutants (HAP) used as the calibration gas
shall be the single organic HAP representing the largest per cent by volume of
the emissions. The use of method 25A is acceptable if the response from the
high-level calibration gas is at least twenty times the standard deviation of
the response from the zero calibration gas when the instrument is zeroed on the
most sensitive scale.
(c)
Each performance test shall consist of three separate
runs; each run conducted for at least one hour under the conditions that exist
when the hazardous secondary material management unit is operating at the
highest load or capacity level reasonably expected to occur. For the purpose of
determining total organic compound concentrations and mass flow rates, the
average of results of all runs shall apply. The average shall be computed on a
time-weighted basis.
(d)
Total organic mass flow rates shall be determined by
the following equation:
(i)
For sources utilizing method 18.
Click to view image
Where:
Eh = Total organic mass flow rate, kilograms per hour (kg/h);
Q2sd = Volumetric flow rate of gases entering or exiting control device, as determined by method 2, standard cubic meter of dry gas per hour (dscm/h);
n = Number of organic compounds in the vent gas;
Ci = Organic concentration in ppm, dry basis, of compound i in the vent gas, as determined by method 18;
MWi = Molecular weight of organic compound i in the vent gas, kilogram per kilogram mole (kg/kg-mol);
0.0416 = Conversion factor for molar volume, kilogram mole per cubic meter (kg-mol/m3) [at two hundred ninety-three Kelvin and seven hundred sixty milligrams of mercury (mm Hg)];
10-6 = Conversion from ppm.
(ii)
For sources
utilizing method 25A.
Eh = (Q)(C)(MW)(0.0416) (10-6)
Where:
Eh = Total organic mass flow rate, kg/h;
Q = Volumetric flow rate of gases entering or exiting control device, as determined by method 2, dscm/h;
C = Organic concentration in ppm, dry basis, as determined by method 25A;
MW = Molecular weight of propane, 44;
0.0416= Conversion factor for molar volume, kg-mol/m3 [at two hundred ninety-three Kelvin and seven hundred sixty mm Hg];
10-6 = Conversion from ppm.
(e)
The annual total
organic emission rate shall be determined by the following equation:
EA = (Eh)(H)
Where:
EA = Total organic mass emission rate, kilograms per year (kg/y);
Eh = Total organic mass flow rate for the process vent, kg/h;
H = Total annual hours of operations for the affected unit, h.
(f)
Total organic
emissions from all affected process vents at the facility shall be determined
by summing the hourly total organic mass emission rates
[Eh, as determined in paragraph (C)(1)(d) of this rule]
and by summing the annual total organic mass emission rates
[EA, as determined in paragraph (C)(1)(e) of this rule]
for all affected process vents at the facility.
(2)
The
remanufacturer or other person who stores or treats the hazardous secondary
material shall record such process information as may be necessary to determine
the conditions of the performance tests. Operations during periods of startup,
shutdown, and malfunction shall not constitute representative conditions for
the purpose of a performance test.
(3)
The
remanufacturer or other person who stores or treats the hazardous secondary
material at an affected facility shall provide, or cause to be provided,
performance testing facilities as follows:
(a)
Sampling ports
adequate for the test methods specified in paragraph (C)(1) of this
rule.
(b)
Safe sampling platforms.
(c)
Safe access to
sampling platforms.
(d)
Utilities for sampling and testing
equipment.
(4)
For the purpose of making compliance determinations,
the time-weighted average of the results of the three runs shall apply. In the
event that a sample is accidentally lost or conditions occur in which one of
the three runs shall be discontinued because of forced shutdown, failure of an
irreplaceable portion of the sample train, extreme meteorological conditions,
or other circumstances beyond the remanufacturer's or other person's that
stores or treats the hazardous secondary material control, compliance may, upon
the director's approval, be determined using the average of the results of the
two other runs.
(D)
To show that a process vent associated with a hazardous
secondary material distillation, fractionation, thin-film evaporation, solvent
extraction, or air or steam stripping operation is not subject to the
requirements of rules
3745-51-730 to
3745-51-735 of the
Administrative Code, the remanufacturer or other person who stores or treats
the hazardous secondary material shall make an initial determination that the
time-weighted, annual average total organic concentration of the material
managed by the hazardous secondary material management unit is less than ten
parts per million by weight (ppmw) using one of the following two
methods:
(1)
Direct measurement of the organic concentration of the material using the
following procedures:
(a)
The remanufacturer or other person who stores or treats
the hazardous secondary material shall take a minimum of four grab samples of
material for each material stream managed in the affected unit under process
conditions expected to cause the maximum material organic
concentration.
(b)
For material generated on-site, the grab samples shall
be collected at a point before the material is exposed to the atmosphere such
as in an enclosed pipe or other closed system that is used to transfer the
material after generation to the first affected distillation, fractionation,
thin-film evaporation, solvent extraction, or air or steam stripping operation.
For material generated offsite, the grab samples shall be collected at the
inlet to the first material management unit that receives the material provided
the material has been transferred to the facility in a closed system such as a
tank truck and the material is not diluted or mixed with other
material.
(c)
Each sample shall be analyzed and the total organic
concentration of the sample shall be computed using method 9060A of "Test
Methods for Evaluating Solid Waste, Physical/Chemical Methods," U.S. EPA
Publication SW-846, or analyzed for the sample's individual organic
constituents.
(d)
The arithmetic mean of the results of the analyses of
the four samples shall apply for each material stream managed in the unit in
determining the time-weighted, annual average total organic concentration of
the material. The time-weighted average is to be calculated using the annual
quantity of each material stream processed and the mean organic concentration
of each material stream managed in the unit.
(2)
Using knowledge
of the material to determine that the material's total organic concentration is
less than ten ppmw. Documentation of the material determination is required.
Examples of documentation that shall be used to support a determination under
this provision include production process information documenting that no
organic compounds are used, information that the material is generated by a
process that is identical to a process at the same or another facility that has
previously been demonstrated by direct measurement to generate a material
stream having a total organic content less than ten ppmw, or prior speciation
analysis results on the same material stream where it also can be documented
that no process changes have occurred since that analysis that could affect the
material total organic concentration.
(E)
The determination
that distillation, fractionation, thin-film evaporation, solvent extraction, or
air or steam stripping operations manage hazardous secondary materials with
time-weighted, annual average total organic concentrations less than ten ppmw
shall be made as follows:
(1)
By the effective date that the facility becomes subject
to rules
3745-51-730 to
3745-51-735 of the
Administrative Code or by the date when the material is first managed in a
hazardous secondary material management unit, whichever is later;
and
(2)
For continuously generated material, annually;
or
(3)
Whenever there is a change in the material being
managed or a change in the process that generates or treats the
material.
(F)
When a remanufacturer or other person who stores or
treats the hazardous secondary material and the director do not agree on
whether a distillation, fractionation, thin-film evaporation, solvent
extraction, or air or steam stripping operation manages a hazardous secondary
material with organic concentrations of at least ten ppmw based on knowledge of
the material, the dispute may be resolved by using direct measurement as
specified at paragraph (D)(1) of this rule.
[Comment: For dates of non-regulatory government publications, publications of recognized organizations and associations, federal rules, and federal statutory provisions referenced in this rule, see rule 3745-50-11 of the Administrative Code titled "Incorporated by reference."]
Notes
Five Year Review (FYR) Dates: Exempt
Promulgated Under: 119.03
Statutory Authority: 3734.12
Rule Amplifies: 3734.12
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