Tenn. Comp. R. & Regs. 1200-03-16-.50 - PHOSPHATE ROCK PLANTS
(1) Applicability.
(a) The provisions of this rule are
applicable to the following affected facilities used in phosphate rock plants
which have a maximum plant production capacity greater than 3.6 megagrams per
hour (4 tons/hr): dryers, calciners, grinders, and ground rock handling and
storage facilities, except those facilities producing or preparing phosphate
rock solely for consumption in elemental phosphorus production.
(b) Any facility under subparagraph (a) of
this paragraph which commences construction, modification, or reconstruction
after November 6, 1988 is subject to the requirements of this rule.
(2) Definitions.
(a) "Phosphate rock plant" means any plant
which produces or prepares phosphate rock product by any or all of the
following processes: Mining, beneficiation, crushing, screening, cleaning,
drying, calcining, and grinding.
(b) "Phosphate rock feed" means all material
entering the process unit including, moisture and extraneous material as well
as the following ore minerals: Fluorapatite, hydroxylapatite, chlorapatite, and
carbonateapatite.
(c) "Dryer" means
a unit in which the moisture content of phosphate rock is reduced by contact
with a heated gas stream.
(d)
"Calciner" means a unit in which the moisture and organic matter of phosphate
rock is reduced within a combustion chamber.
(e) "Grinder" means a unit which is used to
pulverize dry phosphate rock to the final product size used in the manufacture
of phosphate fertilizer and does not include crushing devices used in
mining.
(f) "Ground phosphate rock
handling and storage system" means a system which is used for the conveyance
and storage of ground phosphate rock from grinders at phosphate rock
plants.
(g) "Beneficiation" means
the process of washing the rock to remove impurities or to separate size
fractions.
(3)
Standards:
(a) On and after the date on which
the performance test required to be conducted by paragraph 1200-3-16-.01(5) is
completed, no owner or operator subject to the provisions of this rule shall
cause to be discharged into the atmosphere:
1.
From any phosphate rock dryer any gases which:
(i) Contain particulate matter in excess of
0.030 kilogram per megagram of phosphate rock feed (0.06 lb/ton), or
(ii) Exhibit greater than 10 percent
opacity.
2. From any
phosphate rock calciner processing unbeneficiated rock or blends of
beneficiated and unbeneficiated rock, any gases which:
(i) Contains particulate matter in excess of
0.12 kilogram per megagram of phosphate rock feed (0.23 lb/ton), or
(ii) Exhibit greater than 10 percent
opacity.
3. From any
phosphate rock calciner processing beneficiated rock any gases which:
(i) Contain particulate matter in excess of
0.055 kilogram per megagram of phosphate rock feed (0.11 lb/ton), or
(ii) Exhibit greater than 10 percent
opacity.
4. From any
phosphate rock grinder any gases which:
(i)
Contain particulate matter in excess of 0.006 kilogram per megagram of
phosphate rock feed (0.012 lb/ton), or
(ii) Exhibit greater than zero-percent
opacity.
5. From any
ground phosphate rock handling and storage system any gases which exhibit
greater than zero-percent opacity.
(4) Monitoring of emissions and operations:
(a) Any owner or operator subject to the
provisions of this rule shall install, calibrate, maintain, and operate a
continuous monitoring system, except as provided in subparagraphs (b) and (c)
of this paragraph, to monitor and record the opacity of the gases discharged
into the atmosphere from any phosphate rock dryer, calciner, or grinder. The
span of this system shall be set at 40 percent opacity.
(b) For ground phosphate rock storage and
handling systems, continuous monitoring systems for measuring opacity are not
required.
(c) The owner or operator
of any affected phosphate rock facility using a wet scrubbing emission control
device shall not be subject to the requirements in subparagraph (a) of this
paragraph, but shall install, calibrate, maintain, and operate the following
continuous monitoring devices:
1. A
monitoring device for the continuous measurement of the pressure loss of the
gas stream through the scrubber. The monitoring device must be certified by the
manufacturer to be accurate within ±250 pascals (±1 inch water) gauge
pressure.
2. A monitoring device
for the continuous measurement of the scrubbing liquid supply pressure to the
control device. The monitoring device must be accurate within ±5 percent of
design scrubbing liquid supply pressure.
(d) For the purpose of conducting a
performance test under paragraph 1200-3-16-.01(5), the owner or operator of any
phosphate rock plant subject to the provisions of this rule shall install,
calibrate, maintain, and operate a device for measuring the phosphate rock feed
to any affected dryer, calciner, or grinder. The measuring device used must be
accurate to within ±5 percent of the mass rate over its operating
range.
(e) For the purpose of
reports required under subparagraph 1200-3-16-.01(7)(c), periods of excess
emissions that shall be reported are defined as all 6-minute periods during
which the average opacity of the plume from any phosphate rock dryer, calciner,
or grinder subject to subparagraph (a) of this paragraph exceeds the applicable
opacity limit.
(f) Any owner or
operator subject to the requirements under subparagraph (c) of this paragraph
shall report for each calendar quarter all measurement results that are less
than 90 percent of the average levels maintained during the most recent
performance test conducted under paragraph 1200-3-16-.01(5) in which the
affected facility demonstrated compliance with the standard under paragraph (3)
of this rule.
(5) Test
methods and procedures:
(a) Reference
methods, (as specified in rule 1200-3-16-.01(5)(g) ) except as provided under
subparagraph 1200-3-16-.01(5)(b), shall be used to determine compliance with
paragraph (3) of this rule as follows:
1.
Method 5 for the measurement of particulate matter and associated moisture
content,
2. Method 1 for sample and
velocity traverses,
3. Method 2 for
velocity and volumetric flow rates,
4. Method 3 for gas analysis, and
5. Method 9 for the measurement of the
opacity of emissions.
(b) For Method 5, the sampling time for each
run shall be at least 60 minutes and have a minimum sampled volume of 0.84 dscm
(30 dscf). However, shorter sampling times and smaller sample volumes, when
necessitated by process variables or other factors, may be approved by the
Technical Secretary.
(c) For each
run, the average phosphate rock feed rate in megagrams per hour shall be
determined using a device meeting the requirements of subparagraph (4)(d) of
this rule.
(d) For each run,
emissions expressed in kilograms per megagram of phosphate rock feed shall be
determined using the following equation:
Click to view Image
where:
E= Emissions of particulates in kg/Mg of phosphate rock feed.
Cs= Concentration of particulates in mg/dscm as measured by Method 5.
Qs= Volumetric flow rate in dscm/hr as determined by Method 2.
10-6= Conversion factor for milligrams to kilograms.
M= Average phosphate rock feed rate in Mg/hr.
Notes
Authority: T.C.A. §§ 68-25-108 and 4-5-202.
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