40 CFR Appendix D to Part 122, NPDES Permit Application Testing Requirements (§ 122.21)

Appendix D to Part 122 - NPDES Permit Application Testing Requirements (§ 122.21)

Table I - Testing Requirements for Organic Toxic Pollutants by Industrial Category for Existing Dischargers

Industrial category GC/MS Fraction 1
Volatile Acid Base/neutral Pesticide
Adhesives and Sealants 2 2 2
Aluminum Forming 2 2 2
Auto and Other Laundries 2 2 2 2
Battery Manufacturing 2 2
Coal Mining 2 2 2 2
Coil Coating 2 2 2
Copper Forming 2 2 2
Electric and Electronic Components 2 2 2 2
Electroplating 2 2 2
Explosives Manufacturing 2 2
Foundries 2 2 2
Gum and Wood Chemicals 2 2 2 2
Inorganic Chemicals Manufacturing 2 2 2
Iron and Steel Manufacturing 2 2 2
Leather Tanning and Finishing 2 2 2 2
Mechanical Products Manufacturing 2 2 2
Nonferrous Metals Manufacturing 2 2 2 2
Ore Mining 2 2 2 2
Organic Chemicals Manufacturing 2 2 2 2
Paint and Ink Formulation 2 2 2 2
Pesticides 2 2 2 2
Petroleum Refining 2 2 2 2
Pharmaceutical Preparations 2 2 2
Photographic Equipment and Supplies 2 2 2 2
Plastic and Synthetic Materials Manufacturing 2 2 2 2
Plastic Processing 2
Porcelain Enameling 2 2 2
Printing and Publishing 2 2 2 2
Pulp and Paper Mills 2 2 2 2
Rubber Processing 2 2 2
Soap and Detergent Manufacturing 2 2 2
Steam Electric Power Plants 2 2 2
Textile Mills 2 2 2 2
Timber Products Processing 2 2 2 2

1 The toxic pollutants in each fraction are listed in Table II.

2 Testing required.

Table II - Organic Toxic Pollutants in Each of Four Fractions in Analysis by Gas Chromatography/Mass Spectroscopy (GS/MS)
Volatiles
1V acrolein
2V acrylonitrile
3V benzene
5V bromoform
6V carbon tetrachloride
7V chlorobenzene
8V chlorodibromomethane
9V chloroethane
10V 2-chloroethylvinyl ether
11V chloroform
12V dichlorobromomethane
14V 1,1-dichloroethane
15V 1,2-dichloroethane
16V 1,1-dichloroethylene
17V 1,2-dichloropropane
18V 1,3-dichloropropylene
19V ethylbenzene
20V methyl bromide
21V methyl chloride
22V methylene chloride
23V 1,1,2,2-tetrachloroethane
24V tetrachloroethylene
25V toluene
26V 1,2-trans-dichloroethylene
27V 1,1,1-trichloroethane
28V 1,1,2-trichloroethane
29V trichloroethylene
31V vinyl chloride
Acid Compounds
1A 2-chlorophenol
2A 2,4-dichlorophenol
3A 2,4-dimethylphenol
4A 4,6-dinitro-o-cresol
5A 2,4-dinitrophenol
6A 2-nitrophenol
7A 4-nitrophenol
8A p-chloro-m-cresol
9A pentachlorophenol
10A phenol
11A 2,4,6-trichlorophenol
Base/Neutral
1B acenaphthene
2B acenaphthylene
3B anthracene
4B benzidine
5B benzo(a)anthracene
6B benzo(a)pyrene
7B 3,4-benzofluoranthene
8B benzo(ghi)perylene
9B benzo(k)fluoranthene
10B bis(2-chloroethoxy)methane
11B bis(2-chloroethyl)ether
12B bis(2-chloroisopropyl)ether
13B bis (2-ethylhexyl)phthalate
14B 4-bromophenyl phenyl ether
15B butylbenzyl phthalate
16B 2-chloronaphthalene
17B 4-chlorophenyl phenyl ether
18B chrysene
19B dibenzo(a,h)anthracene
20B 1,2-dichlorobenzene
21B 1,3-dichlorobenzene
22B 1,4-dichlorobenzene
23B 3,3′-dichlorobenzidine
24B diethyl phthalate
25B dimethyl phthalate
26B di-n-butyl phthalate
27B 2,4-dinitrotoluene
28B 2,6-dinitrotoluene
29B di-n-octyl phthalate
30B 1,2-diphenylhydrazine (as azobenzene)
31B fluroranthene
32B fluorene
33B hexachlorobenzene
34B hexachlorobutadiene
35B hexachlorocyclopentadiene
36B hexachloroethane
37B indeno(1,2,3-cd)pyrene
38B isophorone
39B napthalene
40B nitrobenzene
41B N-nitrosodimethylamine
42B N-nitrosodi-n-propylamine
43B N-nitrosodiphenylamine
44B phenanthrene
45B pyrene
46B 1,2,4-trichlorobenzene
Pesticides
1P aldrin
2P alpha-BHC
3P beta-BHC
4P gamma-BHC
5P delta-BHC
6P chlordane
7P 4,4′-DDT
8P 4,4′-DDE
9P 4,4′-DDD
10P dieldrin
11P alpha-endosulfan
12P beta-endosulfan
13P endosulfan sulfate
14P endrin
15P endrin aldehyde
16P heptachlor
17P heptachlor epoxide
18P PCB-1242
19P PCB-1254
20P PCB-1221
21P PCB-1232
22P PCB-1248
23P PCB-1260
24P PCB-1016
25P toxaphene
Table III - Other Toxic Pollutants (Metals and Cyanide) and Total Phenols
Antimony, Total
Arsenic, Total
Beryllium, Total
Cadmium, Total
Chromium, Total
Copper, Total
Lead, Total
Mercury, Total
Nickel, Total
Selenium, Total
Silver, Total
Thallium, Total
Zinc, Total
Cyanide, Total
Phenols, Total
Table IV - Conventional and Nonconventional Pollutants Required To Be Tested by Existing Dischargers if Expected to be Present
Bromide
Chlorine, Total Residual
Color
Fecal Coliform
Fluoride
Nitrate-Nitrite
Nitrogen, Total Organic
Oil and Grease
Phosphorus, Total
Radioactivity
Sulfate
Sulfide
Sulfite
Surfactants
Aluminum, Total
Barium, Total
Boron, Total
Cobalt, Total
Iron, Total
Magnesium, Total
Molybdenum, Total
Manganese, Total
Tin, Total
Titanium, Total
Table V - Toxic Pollutants and Hazardous Substances Required To Be Identified by Existing Dischargers if Expected To Be Present
Toxic Pollutants
Asbestos
Hazardous Substances
Acetaldehyde
Allyl alcohol
Allyl chloride
Amyl acetate
Aniline
Benzonitrile
Benzyl chloride
Butyl acetate
Butylamine
Captan
Carbaryl
Carbofuran
Carbon disulfide
Chlorpyrifos
Coumaphos
Cresol
Crotonaldehyde
Cyclohexane
2,4-D (2,4-Dichlorophenoxy acetic acid)
Diazinon
Dicamba
Dichlobenil
Dichlone
2,2-Dichloropropionic acid
Dichlorvos
Diethyl amine
Dimethyl amine
Dintrobenzene
Diquat
Disulfoton
Diuron
Epichlorohydrin
Ethion
Ethylene diamine
Ethylene dibromide
Formaldehyde
Furfural
Guthion
Isoprene
Isopropanolamine Dodecylbenzenesulfonate
Kelthane
Kepone
Malathion
Mercaptodimethur
Methoxychlor
Methyl mercaptan
Methyl methacrylate
Methyl parathion
Mevinphos
Mexacarbate
Monoethyl amine
Monomethyl amine
Naled
Napthenic acid
Nitrotoluene
Parathion
Phenolsulfanate
Phosgene
Propargite
Propylene oxide
Pyrethrins
Quinoline
Resorcinol
Strontium
Strychnine
Styrene
2,4,5-T (2,4,5-Trichlorophenoxy acetic acid)
TDE (Tetrachlorodiphenylethane)
2,4,5-TP [2-(2,4,5-Trichlorophenoxy) propanoic acid]
Trichlorofan
Triethanolamine dodecylbenzenesulfonate
Triethylamine
Trimethylamine
Uranium
Vanadium
Vinyl acetate
Xylene
Xylenol
Zirconium

[Note 1: The Environmental Protection Agency has suspended the requirements of § 122.21(g)(7)(ii)(A) and Table I of Appendix D as they apply to certain industrial categories. The suspensions are as follows:

a. At 46 FR 2046, Jan. 8, 1981, the Environmental Protection Agency suspended until further notice § 122.21(g)(7)(ii)(A) as it applies to coal mines.

b. At 46 FR 22585, Apr. 20, 1981, the Environmental Protection Agency suspended until further notice § 122.21(g)(7)(ii)(A) and the corresponding portions of Item V-C of the NPDES application Form 2c as they apply to:

1. Testing and reporting for all four organic fractions in the Greige Mills Subcategory of the Textile Mills industry (Subpart C - Low water use processing of 40 CFR part 410), and testing and reporting for the pesticide fraction in all other subcategories of this industrial category.

2. Testing and reporting for the volatile, base/neutral and pesticide fractions in the Base and Precious Metals Subcategory of the Ore Mining and Dressing industry (subpart B of 40 CFR part 440), and testing and reporting for all four fractions in all other subcategories of this industrial category.

3. Testing and reporting for all four GC/MS fractions in the Porcelain Enameling industry.

c. At 46 FR 35090, July 1, 1981, the Environmental Protection Agency suspended until further notice § 122.21(g)(7)(ii)(A) and the corresponding portions of Item V-C of the NPDES application Form 2c as they apply to:

1. Testing and reporting for the pesticide fraction in the Tall Oil Rosin Subcategory (subpart D) and Rosin-Based Derivatives Subcategory (subpart F) of the Gum and Wood Chemicals industry ( 40 CFR part 454), and testing and reporting for the pesticide and base/netural fractions in all other subcategories of this industrial category.

2. Testing and reporting for the pesticide fraction in the Leather Tanning and Finishing, Paint and Ink Formulation, and Photographic Supplies industrial categories.

3. Testing and reporting for the acid, base/neutral and pesticide fractions in the Petroleum Refining industrial category.

4. Testing and reporting for the pesticide fraction in the Papergrade Sulfite subcategories (subparts J and U) of the Pulp and Paper industry ( 40 CFR part 430); testing and reporting for the base/neutral and pesticide fractions in the following subcategories: Deink (subpart Q), Dissolving Kraft (subpart F), and Paperboard from Waste Paper (subpart E); testing and reporting for the volatile, base/neutral and pesticide fractions in the following subcategories: BCT Bleached Kraft (subpart H), Semi-Chemical (subparts B and C), and Nonintegrated-Fine Papers (subpart R); and testing and reporting for the acid, base/neutral, and pesticide fractions in the following subcategories: Fine Bleached Kraft (subpart I), Dissolving Sulfite Pulp (subpart K), Groundwood-Fine Papers (subpart O), Market Bleached Kraft (subpart G), Tissue from Wastepaper (subpart T), and Nonintegrated-Tissue Papers (subpart S).

5. Testing and reporting for the base/neutral fraction in the Once-Through Cooling Water, Fly Ash and Bottom Ash Transport Water process wastestreams of the Steam Electric Power Plant industrial category.

This revision continues these suspensions.]*

* Editorial Note: The words “This revision” refer to the document published at 48 FR 14153, Apr. 1, 1983.

For the duration of the suspensions, therefore, Table I effectively reads:

Table I - Testing Requirements for Organic Toxic Pollutants by Industry Category

Industry category GC/MS fraction 2
Volatile Acid Neutral Pesticide
Adhesives and sealants ( 1) ( 1) ( 1)
Aluminum forming ( 1) ( 1) ( 1)
Auto and other laundries ( 1) ( 1) ( 1) ( 1)
Battery manufacturing ( 1) ( 1)
Coal mining
Coil coating ( 1) ( 1) ( 1)
Copper forming ( 1) ( 1) ( 1)
Electric and electronic compounds ( 1) ( 1) ( 1) ( 1)
Electroplating ( 1) ( 1) ( 1)
Explosives manufacturing ( 1) ( 1)
Foundries ( 1) ( 1) ( 1)
Gum and wood (all subparts except D and F) ( 1) ( 1)
Subpart D - tall oil rosin ( 1) ( 1) ( 1)
Subpart F - rosin-based derivatives ( 1) ( 1) ( 1)
Inorganic chemicals manufacturing ( 1) ( 1) ( 1)
Iron and steel manufacturing ( 1) ( 1) ( 1)
Leather tanning and finishing ( 1) ( 1) ( 1)
Mechanical products manufacturing ( 1) ( 1) ( 1)
Nonferrous metals manufacturing ( 1) ( 1) ( 1) ( 1)
Ore mining (applies to the base and precious metals/Subpart B) ( 1)
Organic chemicals manufacturing ( 1) ( 1) ( 1) ( 1)
Paint and ink formulation ( 1) ( 1) ( 1)
Pesticides ( 1) ( 1) ( 1) ( 1)
Petroleum refining ( 1)
Pharmaceutical preparations ( 1) ( 1) ( 1)
Photographic equipment and supplies ( 1) ( 1) ( 1)
Plastic and synthetic materials manufacturing ( 1) ( 1) ( 1) ( 1)
Plastic processing ( 1)
Porcelain enameling
Printing and publishing ( 1) ( 1) ( 1) ( 1)
Pulp and paperboard mills - see footnote 3
Rubber processing ( 1) ( 1) ( 1)
Soap and detergent manufacturing ( 1) ( 1) ( 1)
Steam electric power plants ( 1) ( 1)
Textile mills (Subpart C - Greige Mills are exempt from this table) ( 1) ( 1) ( 1)
Timber products processing ( 1) ( 1) ( 1) ( 1)

1 Testing required.

2 The pollutants in each fraction are listed in Item V-C.

3 Pulp and Paperboard Mills:

Subpart 3 GS/MS fractions
VOA Acid Base/neutral Pesticides
A 2 ( 1) 2 ( 1)
B 2 ( 1) 2 2
C 2 ( 1) 2 2
D 2 ( 1) 2 2
E ( 1) ( 1) 2 ( 1)
F ( 1) ( 1) 2 2
G ( 1) ( 1) 2 2
H ( 1) ( 1) 2 2
I ( 1) ( 1) 2 2
J ( 1) ( 1) ( 1) 2
K ( 1) ( 1) 2 2
L ( 1) ( 1) 2 2
M ( 1) ( 1) 2 2
N ( 1) ( 1) 2 2
O ( 1) ( 1) 2 2
P ( 1) ( 1) 2 2
Q ( 1) ( 1) 2 ( 1)
R 2 ( 1) 2 2
S ( 1) ( 1) 2 ( 1)
T ( 1) ( 1) 2 ( 1)
U ( 1) ( 1) ( 1) 2

1 Must test.

2 Do not test unless “reason to believe” it is discharged.

3 Subparts are defined in 40 CFR Part 430.

[ 48 FR 14153, Apr. 1, 1983, as amended at 49 FR 38050, Sept. 26, 1984; 50 FR 6940, Feb. 19, 1985]

This is a list of United States Code sections, Statutes at Large, Public Laws, and Presidential Documents, which provide rulemaking authority for this CFR Part.

This list is taken from the Parallel Table of Authorities and Rules provided by GPO [Government Printing Office].

It is not guaranteed to be accurate or up-to-date, though we do refresh the database weekly. More limitations on accuracy are described at the GPO site.


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U.S. Code: Title 33 - NAVIGATION AND NAVIGABLE WATERS
U.S. Code: Title 42 - THE PUBLIC HEALTH AND WELFARE