Ohio Admin. Code 3745-66-99 - Special requirements for incompatible wastes

(A) Incompatible wastes, or incompatible wastes and materials (see the Appendix of this rule for examples), shall not be placed in the same tank system, unless paragraph (B) of rule 3745-65-17 of the Administrative Code is complied with.
(B) Hazardous waste shall not be placed in a tank system that has not been decontaminated and that previously held in incompatible waste or material, unless paragraph (B) of rule 3745-65-17 of the Administrative Code is complied with.

Appendix to 3745-66-99

[Note: This appendix is equivalent to Appendix V of 40 CFR Part 265.]

Examples of Potentially Incompatible Waste

Many hazardous wastes, when mixed with other waste or materials at a hazardous waste facility, can produce effects which are harmful to human health and the environment, such as: heat or pressure; fire or explosion; violent reaction, toxic dusts, mists, fumes, or gases; or flammable fumes or gases.

Below are examples of potentially incompatible wastes, waste components, and materials, along with the harmful consequences which result from mixing materials in one group with materials in another group. The list is intended as a guide to owners or operators of treatment, storage, and disposal facilities, and to enforcement and permit granting officials, to indicate the need for special precautions when managing these potentially incompatible waste materials or components.

This list is not intended to be exhaustive. An owner or operator must, as the regulations require, adequately analyze his wastes so that he can avoid creating uncontrolled substances or reactions of the type listed below, whether they are listed below or not.

It is possible for potentially incompatible wastes to be mixed in a way that precludes a reaction (e.g., adding acid to water rather than water to acid) or that neutralizes them (e.g., a strong acid mixed with a strong base), or that controls substances produced (e.g., by generating flammable gases in a closed tank equipped so that ignition cannot occur, and burning the gases in an incinerator).

In the lists below, the mixing of a group A material with a group B material may have the potential consequence as noted. Group 1-A

Acetylene sludge

Alkaline caustic liquids

Alkaline cleaner

Alkaline corrosive liquids

Alkaline corrosive battery fluid

Caustic wastewater

Lime sludge and other corrosive alkalies

Lime wastewater

Lime and water

Spent caustic Group 1-B

Acid sludge

Acid and water

Battery acid

Chemical cleaners

Electrolyte acid

Etching acid liquid or solvent

Pickling liquor and other corrosive acids

Spent acid

Spent mixed acid

Spent sulfuric acid

Potential consequences: heat generation; violent reaction. Group 2-A








Zinc powder

Other reactive metals and metal hydrides

Any waste in Group 1-A or 1-B

Potential consequences: fire or explosion; generation of flammable hydrogen gas. Group 3-A


Water Group 3-B

Any concentrated waste in Groups 1-A or 1-B



Metal hydrides


SO2C12, SOC12, PC13, CH3SiC13

Other water-reactive waste

Potential consequences: fire, explosion, or heat generation; generation of flammable or toxic gases. Group 4-A



Halogenated hydrocarbons

Nitrated hydrocarbons

Unsaturated hydrocarbons

Other reactive organic compounds and solvents Group 4-B

Concentrated Group 1-A or 1-B wastes

Group 2-A wastes

Potential consequences: fire, explosion, or violent reaction. Group 5-A

Spent cyanide and sulfide solutions Group 5-B

Group 1-B wastes

Potential consequences: generation of toxic hydrogen cyanide or hydrogen sulfide gas. Group 6-A




Chromic acid



Nitric acid, fuming




Other strong oxidizers Group 6-B

Acetic acid and other organic acids

Concentrated mineral acids

Group 2-A wastes

Group 4-A wastes

Other flammable and combustible wastes

Potential consequences: fire, explosion, or violent reaction.


Ohio Admin. Code 3745-66-99
Eff 4-15-81; 1-7-83; 12-8-88
Rule promulgated under: RC Chapter 119.
Rule amplifies: RC 3734.12

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