(a) Waste determination procedure to
determine average volatile organic (VO) concentration of a hazardous waste at
the point of waste origination.
(1) An owner
or operator shall determine the average VO concentration at the point of waste
origination for each hazardous waste placed in a waste management unit exempted
under the provisions of Subsection R315-265-1083(c)(1) from using air emission
controls in accordance with standards specified in Sections R315-265-1085
through R315-265-1088, as applicable to the waste management unit.
(i) An initial determination of the average
VO concentration of the waste stream shall be made before the first time any
portion of the material in the hazardous waste stream is placed in a waste
management unit exempted under the provisions of Subsection R315-265-1083(c)(1)
from using air emission controls, and thereafter an initial determination of
the average VO concentration of the waste stream shall be made for each
averaging period that a hazardous waste is managed in the unit; and
(ii) Perform a new waste determination if
changes to the source generating the waste stream are reasonably likely to
cause the average VO concentration of the hazardous waste to increase to a
level that is equal to or greater than the VO concentration limit specified in
Subsection R315-265-1083(c)(1).
(2) For a waste determination that is
required by Subsection R315-265-1084(a)(1), the average VO concentration of a
hazardous waste at the point of waste origination shall be determined using
either direct measurement as specified in Subsection R315-265-1084(a)(3) or by
knowledge as specified in Subsection R315-265-1084(a)(4).
(3) Direct measurement to determine average
VO concentration of a hazardous waste at the point of waste origination.
(i) Identification. The owner or operator
shall identify and record the point of waste origination for the hazardous
waste.
(ii) Sampling. Samples of
the hazardous waste stream shall be collected at the point of waste origination
in a manner such that volatilization of organics contained in the waste and in
the subsequent sample is minimized and an adequately representative sample is
collected and maintained for analysis by the selected method.
(A) The averaging period to be used for
determining the average VO concentration for the hazardous waste stream on a
mass-weighted average basis shall be designated and recorded. The averaging
period can represent any time interval that the owner or operator determines is
appropriate for the hazardous waste stream but shall not exceed 1
year.
(B) A sufficient number of
samples, but no less than four samples, shall be collected and analyzed for a
hazardous waste determination. All of the samples for a given waste
determination shall be collected within a one-hour period. The average of the
four or more sample results constitutes a waste determination for the waste
stream. One or more waste determinations may be required to represent the
complete range of waste compositions and quantities that occur during the
entire averaging period due to normal variations in the operating conditions
for the source or process generating the hazardous waste stream. Examples of
such normal variations are seasonal variations in waste quantity or
fluctuations in ambient temperature.
(C) All samples shall be collected and
handled in accordance with written procedures prepared by the owner or operator
and documented in a site sampling plan. This plan shall describe the procedure
by which representative samples of the hazardous waste stream are collected
such that a minimum loss of organics occurs throughout the sample collection
and handling process, and by which sample integrity is maintained. A copy of
the written sampling plan shall be maintained on-site in the facility operating
records. An example of acceptable sample collection and handling procedures for
a total volatile organic constituent concentration may be found in Method 25D
in 40 CFR part
60, appendix A.
(D)
Sufficient information, as specified in the "site sampling plan" required under
Subsection R315-265-1084(a)(3)(ii)(C), shall be prepared and recorded to
document the waste quantity represented by the samples and, as applicable, the
operating conditions for the source or process generating the hazardous waste
represented by the samples.
(iii) Analysis. Each collected sample shall
be prepared and analyzed in accordance with Method 25D in 40 CFR part
60,
appendix A for the total concentration of volatile organic constituents, or
using one or more methods if the individual organic compound concentrations are
identified and summed and the summed waste concentration accounts for and
reflects all organic compounds in the waste with Henry's law constant values at
least 0.1 mole-fraction-in-the-gas-phase/mole-fraction-in-the-liquid-phase (0.1
Y/X), which can also be expressed as 1.8 × 10-6 atmospheres/gram-mole/m3,
at 25 degrees Celsius. At the owner or operator's discretion, the owner or
operator may adjust test data obtained by any appropriate method to discount
any contribution to the total volatile organic concentration that is a result
of including a compound with a Henry's law constant value of less than 0.1 Y/X
at 25 degrees Celsius. To adjust these data, the measured concentration of each
individual chemical constituent contained in the waste is multiplied by the
appropriate constituent-specific adjustment factor (fm25D). If the owner or
operator elects to adjust test data, the adjustment shall be made to all
individual chemical constituents with a Henry's law constant value greater than
or equal to 0.1 Y/X at 25 degrees Celsius contained in the waste.
Constituent-specific adjustment factors (fm25D) can be obtained by contacting
the Waste and Chemical Processes Group, Office of Air Quality Planning and
Standards, Research Triangle Park, NC 27711. Other test methods may be used if
they meet the requirements in Subsections R315-265-1084(a)(3)(iii)(A) or (B)
and provided the requirement to reflect all organic compounds in the waste with
Henry's law constant values greater than or equal to 0.1 Y/X, which can also be
expressed as 1.8 × 10-6 atmospheres/gram-mole/m3, at 2 5 degrees Celsius,
is met.
(A) Any EPA standard method that has
been validated in accordance with "Alternative Validation Procedure for EPA
Waste and Wastewater Methods," 40 CFR part
63, appendix D.
(B) Any other analysis method that has been
validated in accordance with the procedures specified in Section 5.1 or Section
5.3, and the corresponding calculations in Section 6.1 or Section 6.3, of
Method 301 in 40 CFR part
63, appendix A. The data are acceptable if they meet
the criteria specified in Section 6.1.5 or Section 6.3.3 of Method 301. If
correction is required under section 6.3.3 of Method 301, the data are
acceptable if the correction factor is within the range 0.7 to 1.30. Other
sections of Method 301 are not required.
(iv) Calculations.
(A) The average VO concentration on a
mass-weighted basis shall be calculated by using the results for all waste
determinations conducted in accordance with Subsections R315-265-1084(a)(3)
(ii) and (iii) and the equation found in
40 CFR
265.1084(a)(3)(iv)(A), which
is adopted and incorporated by reference.
(B) For the purpose of determining Ci, for
individual waste samples analyzed in accordance with Subsection
R315-265-1084(a)(3)(iii), the owner or operator shall account for VO
concentrations determined to be below the limit of detection of the analytical
method by using the following VO concentration:
(1) If Method 25D in 40 CFR part
60, appendix
A is used for the analysis, one-half the blank value determined in the method
at section 4.4 of Method 25D in 40 CFR part
60, appendix A.
(2) If any other analytical method is used,
one-half the sum of the limits of detection established for each organic
constituent in the waste that has a Henry's law constant values at least 0.1
mole-fraction-in-the-gas-phase/mole-fraction-in-the-liquid-phase (0.1 Y/X),
which can also be expressed as 1.8 × 10-6 atmospheres/gram-mole/m3, at 25
degrees Celsius.
(v) Provided that the test method is
appropriate for the waste as required under Subsection
R315-265-1084(a)(3)(iii), the Director will determine compliance based on the
test method used by the owner or operator as recorded pursuant to Subsection
R315-265-1090(f)(1).
(4)
Use of owner or operator knowledge to determine average VO concentration of a
hazardous waste at the point of waste origination.
(i) Documentation shall be prepared that
presents the information used as the basis for the owner's or operator's
knowledge of the hazardous waste stream's average VO concentration. Examples of
information that may be used as the basis for knowledge include: Material
balances for the source or process generating the hazardous waste stream;
constituent-specific chemical test data for the hazardous waste stream from
previous testing that are still applicable to the current waste stream;
previous test data for other locations managing the same type of waste stream;
or other knowledge based on information included in manifests, shipping papers,
or waste certification notices.
(ii) If test data are used as the basis for
knowledge, then the owner or operator shall document the test method, sampling
protocol, and the means by which sampling variability and analytical
variability are accounted for in the determination of the average VO
concentration. For example, an owner or operator may use organic concentration
test data for the hazardous waste stream that are validated in accordance with
Method 301 in 40 CFR part
63, appendix A as the basis for knowledge of the
waste.
(iii) An owner or operator
using chemical constituent-specific concentration test data as the basis for
knowledge of the hazardous waste may adjust the test data to the corresponding
average VO concentration value which would have been obtained had the waste
samples been analyzed using Method 25D in 40 CFR part
60, appendix A. To adjust
these data, the measured concentration for each individual chemical constituent
contained in the waste is multiplied by the appropriate constituent-specific
adjustment factor (fm25D).
(iv) In
the event that the Director and the owner or operator disagree on a
determination of the average VO concentration for a hazardous waste stream
using knowledge, then the results from a determination of average VO
concentration using direct measurement as specified in Subsection
R316-265-1084(a)(3) shall be used to establish compliance with the applicable
requirements of Sections R315-265-1080 through R315-265-1090. The Director may
perform or request that the owner or operator perform this determination using
direct measurement. The owner or operator may choose one or more appropriate
methods to analyze each collected sample in accordance with the requirements of
Subsection R315-265-1084(a)(3)(iii).
(b) Waste determination procedures for
treated hazardous waste.
(1) An owner or
operator shall perform the applicable waste determination for each treated
hazardous waste placed in a waste management unit exempted under the provisions
of Subsections R315-265-1083(c)(2)(i) through (c)(2)(vi) from using air
emission controls in accordance with standards specified in Sections
R315-265-1085 through R315-265-1088, as applicable to the waste management
unit.
(i) An initial determination of the
average VO concentration of the waste stream shall be made before the first
time any portion of the material in the treated waste stream is placed in a
waste management unit exempted under the provisions of Subsections
R315-265-1083(c)(2), R315-265-1083(c)(3), or R315-265-1083(c)(4) from using air
emission controls, and thereafter update the information used for the waste
determination at least once every 12 months following the date of the initial
waste determination; and
(ii)
Perform a new waste determination if changes to the process generating or
treating the waste stream are reasonably likely to cause the average VO
concentration of the hazardous waste to increase to a level such that the
applicable treatment conditions specified in Subsections R315-265-1083(c)(2),
R315-265-1083(c)(3), or R315-265-1083(c)(4) are not achieved.
(2) The owner or operator shall
designate and record the specific provision in Subsection R315-265-1083(c)(2)
under which the waste determination is being performed. The waste determination
for the treated hazardous waste shall be performed using the applicable
procedures specified in Subsections R315-265-1084(b)(3) through
(b)(9).
(3) Procedure to determine
the average VO concentration of a hazardous waste at the point of waste
treatment.
(i) Identification. The owner or
operator shall identify and record the point of waste treatment for the
hazardous waste.
(ii) Sampling.
Samples of the hazardous waste stream shall be collected at the point of waste
treatment in a manner such that volatilization of organics contained in the
waste and in the subsequent sample is minimized and an adequately
representative sample is collected and maintained for analysis by the selected
method.
(A) The averaging period to be used
for determining the average VO concentration for the hazardous waste stream on
a mass-weighted average basis shall be designated and recorded. The averaging
period can represent any time interval that the owner or operator determines is
appropriate for the hazardous waste stream but shall not exceed 1
year.
(B) A sufficient number of
samples, but no less than four samples, shall be collected and analyzed for a
hazardous waste determination. All of the samples for a given waste
determination shall be collected within a one-hour period. The average of the
four or more sample results constitutes a waste determination for the waste
stream. One or more waste determinations may be required to represent the
complete range of waste compositions and quantities that occur during the
entire averaging period due to normal variations in the operating conditions
for the process generating or treating the hazardous waste stream. Examples of
such normal variations are seasonal variations in waste quantity or
fluctuations in ambient temperature.
(C) All samples shall be collected and
handled in accordance with written procedures prepared by the owner or operator
and documented in a site sampling plan. This plan shall describe the procedure
by which representative samples of the hazardous waste stream are collected
such that a minimum loss of organics occurs throughout the sample collection
and handling process, and by which sample integrity is maintained. A copy of
the written sampling plan shall be maintained on-site in the facility operating
records. An example of acceptable sample collection and handling procedures for
a total volatile organic constituent concentration may be found in Method 25D
in 40 CFR part
60, appendix A.
(D)
Sufficient information, as specified in the "site sampling plan" required under
Subsection R316-265-1084(b)(3)(ii)(C), shall be prepared and recorded to
document the waste quantity represented by the samples and, as applicable, the
operating conditions for the process treating the hazardous waste represented
by the samples.
(iii)
Analysis. Each collected sample shall be prepared and analyzed in accordance
with Method 25D in 40 CFR part
60, appendix A for the total concentration of
volatile organic constituents, or using one or more methods if the individual
organic compound concentrations are identified and summed and the summed waste
concentration accounts for and reflects all organic compounds in the waste with
Henry's law constant values at least 0.1
mole-fraction-in-the-gas-phase/mole-fraction-in-the-liquid-phase (0.1 Y/X),
which can also be expressed as 1.8 × 10-6 atmospheres/gram-mole/m3, at 25
degrees Celsius. If the owner or operator is making a waste determination for a
treated hazardous waste that is to be compared to an average VO concentration
at the point of waste origination or the point of waste entry to the treatment
system to determine if the conditions of Subsections
R315-264-1082(c)(2)(i) through
(c)(2)(vi), or Subsections
R315-265-1083(c)(2)(i) through (c)(2)(vi) are met, then the waste samples shall
be prepared and analyzed using the same method or methods as were used in
making the initial waste determinations at the point of waste origination or at
the point of entry to the treatment system. At the owner or operator's
discretion, the owner or operator may adjust test data obtained by any
appropriate method to discount any contribution to the total volatile organic
concentration that is a result of including a compound with a Henry's law
constant value less than 0.1 Y/X at 25 degrees Celsius. To adjust these data,
the measured concentration of each individual chemical constituent in the waste
is multiplied by the appropriate constituent-specific adjustment factor
(fm25D). If the owner or operator elects to adjust test data, the adjustment
shall be made to all individual chemical constituents with a Henry's law
constant value greater than or equal to 0.1 Y/X at 25 degrees Celsius contained
in the waste. Constituent-specific adjustment factors (fm25D) can be obtained
by contacting the Waste and Chemical Processes Group, Office of Air Quality
Planning and Standards, Research Triangle Park, NC 27711. Other test methods
may be used if they meet the requirements in Subsections
R315-265-1084(a)(3)(iii)(A) or (B) and provided the requirement to reflect all
organic compounds in the waste with Henry's law constant values greater than or
equal to 0.1 Y/X, which can also be expressed as 1.8 × 10-6
atmospheres/gram-mole/m3, at 25 degrees Celsius, is met.
(A) Any EPA standard method that has been
validated in accordance with "Alternative Validation Procedure for EPA Waste
and Wastewater Methods," 40 CFR part
63, appendix D.
(B) Any other analysis method that has been
validated in accordance with the procedures specified in Section 5.1 or Section
5.3, and the corresponding calculations in Section 6.1 or Section 6.3, of
Method 301 in 40 CFR part
63, appendix A. The data are acceptable if they meet
the criteria specified in Section 6.1.5 or Section 6.3.3 of Method 301. If
correction is required under section 6.3.3 of Method 301, the data are
acceptable if the correction factor is within the range 0.7 to 1.30. Other
sections of Method 301 are not required.
(iv) Calculations. The average VO
concentration on a mass-weighted basis shall be calculated by using the results
for all waste determinations conducted in accordance with Subsections
R315-265-1084(b)(3)(ii) and (iii) and the equation found in
40 CFR
265.1084(b)(3)(iv), which is
adopted and incorporated by reference.
(v) Provided that the test method is
appropriate for the waste as required under Subsection
R315-265-1084(b)(3)(iii), compliance shall be determined based on the test
method used by the owner or operator as recorded pursuant to Subsection
R315-265-1090(f)(1).
(4)
Procedure to determine the exit concentration limit for a treated hazardous
waste.
(i) The point of waste origination for
each hazardous waste treated by the process at the same time shall be
identified.
(ii) If a single
hazardous waste stream is identified in Subsection R315-265-1084(b)(4)(i), then
the exit concentration limit shall be 500 ppmw.
(iii) If more than one hazardous waste stream
is identified in Subsection R315-265-1084(b)(4)(i), then the average VO
concentration of each hazardous waste stream at the point of waste origination
shall be determined in accordance with the requirements of Subsection
R315-265-1084(a). The exit concentration limit shall be calculated by using the
results determined for each individual hazardous waste stream and the equation
found in
40 CFR
265.1084(b)(4)(iii), which
is adopted and incorporated by reference.
(5) Procedure to determine the organic
reduction efficiency for a treated hazardous waste.
(i) The organic reduction efficiency for a
treatment process shall be determined based on results for a minimum of three
consecutive runs.
(ii) All
hazardous waste streams entering the treatment process and all hazardous waste
streams exiting the treatment process shall be identified. The owner or
operator shall prepare a sampling plan for measuring these streams that
accurately reflects the retention time of the hazardous waste in the
process.
(iii) For each run,
information shall be determined for each hazardous waste stream identified in
Subsection R315-265-1084(b)(5)(ii) using the following procedures:
(A) The mass quantity of each hazardous waste
stream entering the process and the mass quantity of each hazardous waste
stream exiting the process shall be determined.
(B) The average VO concentration at the point
of waste origination of each hazardous waste stream entering the process during
the run shall be determined in accordance with the requirements of Subsection
R315-265-1084(a)(3). The average VO concentration at the point of waste
treatment of each waste stream exiting the process during the run shall be
determined in accordance with the requirements of Subsection
R315-265-1084(b)(3).
(iv) The waste volatile organic mass flow
entering the process and the waste volatile organic mass flow exiting the
process shall be calculated by using the results determined in accordance with
Subsection R315-265-1084(b)(5)(iii) and the equations found in
40 CFR
265.1084(b)(5)(iv), which is
adopted and incorporated by reference.
(v) The organic reduction efficiency of the
process shall be calculated by using the results determined in accordance with
Subsection R315-265-1084(b)(5)(iv) and the equation found in
40 CFR
265.1084(b)(5)(v), which is
adopted and incorporated by reference.
(6) Procedure to determine the organic
biodegradation efficiency for a treated hazardous waste.
(i) The fraction of organics biodegraded
shall be determined using the procedure specified in 40 CFR part
63, appendix
C.
(ii) The organic biodegradation
efficiency shall be calculated by using the equation found in
40 CFR
265.1084(b)(6)(ii), which is
adopted and incorporated by reference.
(7) Procedure to determine the required
organic mass removal rate for a treated hazardous waste.
(i) All of the hazardous waste streams
entering the treatment process shall be identified.
(ii) The average VO concentration of each
hazardous waste stream at the point of waste origination shall be determined in
accordance with the requirements of Subsection R315-265-1084(a).
(iii) For each individual hazardous waste
stream that has an average VO concentration equal to or greater than 500 ppmw
at the point of waste origination, the average volumetric flow rate and the
density of the hazardous waste stream at the point of waste origination shall
be determined.
(iv) The required
organic mass removal rate shall be calculated by using the average VO
concentration, average volumetric flow rate, and density determined for each
individual hazardous waste stream, and the equation found in
40 CFR
265.1084(b)(7)(iv), which is
adopted and incorporated by reference.
(8) Procedure to determine the actual organic
mass removal rate (MR) for a treated hazardous waste.
(i) The MR shall be determined based on
results for a minimum of three consecutive runs. The sampling time for each run
shall be 1 hour.
(ii) The waste
volatile organic mass flow entering the process (Eb) and the waste volatile
organic mass flow exiting the process (Ea) shall be determined in accordance
with the requirements of Subsection R315-265-1084(b)(5)(iv).
(iii) The MR shall be calculated by using the
mass flow rate determined in accordance with the requirements of Subsection
R315-265-1084(b)(8)(ii) and the following equation:
MR = Eb -- Ea
Where:
MR = Actual organic mass removal rate, kg/hr.
Eb = Waste volatile organic mass flow entering process as
determined in accordance with the requirements of Subsection
R315-265-1084(b)(5)(iv), kg/hr.
Ea = Waste volatile organic mass flow exiting process as
determined in accordance with the requirements of Subsection
R315-265-1084(b)(5)(iv), kg/hr.
(9) Procedure to determine the actual organic
mass biodegradation rate (MRbio) for a treated hazardous waste.
(i) The MRbio shall be determined based on
results for a minimum of three consecutive runs. The sampling time for each run
shall be 1 hour.
(ii) The waste
organic mass flow entering the process (Eb) shall be determined in accordance
with the requirements of Subsection R315-265-1084(b)(5)(iv).
(iii) The fraction of organic biodegraded
(Fbio) shall be determined using the procedure specified in 40 CFR part
63,
appendix C.
(iv) The MRbio shall be
calculated by using the mass flow rates and fraction of organic biodegraded
determined in accordance with the requirements of Subsections
R315-265-1084(b)(9)(ii) and (b)(9)(iii), respectively, and the following
equation:
MRbio = Eb × Fbio
Where:
MRbio = Actual organic mass biodegradation rate,
kg/hr.
Eb = Waste organic mass flow entering process as determined
in accordance with the requirements of Subsection R315-265-1084(b)(5)(iv),
kg/hr.
Fbio = Fraction of organic biodegraded as determined in
accordance with the requirements of Subsection R315-265-1084(b)(9)(iii).
(c)
Procedure to determine the maximum organic vapor pressure of a hazardous waste
in a tank.
(1) An owner or operator shall
determine the maximum organic vapor pressure for each hazardous waste placed in
a tank using Tank Level 1 controls in accordance with the standards specified
in Subsection R315-265-1085(c).
(2)
An owner or operator shall use either direct measurement as specified in
Subsection R315-265-1084(c)(3) or knowledge of the waste as specified by
Subsection R315-265-1084(c)(4) to determine the maximum organic vapor pressure
which is representative of the hazardous waste composition stored or treated in
the tank.
(3) Direct measurement to
determine the maximum organic vapor pressure of a hazardous waste.
(i) Sampling. A sufficient number of samples
shall be collected to be representative of the waste contained in the tank. All
samples shall be collected and handled in accordance with written procedures
prepared by the owner or operator and documented in a site sampling plan. This
plan shall describe the procedure by which representative samples of the
hazardous waste are collected such that a minimum loss of organics occurs
throughout the sample collection and handling process and by which sample
integrity is maintained. A copy of the written sampling plan shall be
maintained on-site in the facility operating records. An example of acceptable
sample collection and handling procedures may be found in Method 25D in 40 CFR
part
60, appendix A.
(ii)
Analysis. Any appropriate one of the following methods may be used to analyze
the samples and compute the maximum organic vapor pressure of the hazardous
waste:
(A) Method 25E in 40 CFR part
60
appendix A;
(B) Methods described
in American Petroleum Institute Publication 2517, Third Edition, February 1989,
"Evaporative Loss from External Floating-Roof Tanks," incorporated by
reference---refer to Section
R315-260-11;
(C) Methods obtained from standard reference
texts;
(D) ASTM Method 2879-92,
incorporated by reference---refer to Section
R315-260-11;
and
(E) Any other method approved
by the Director.
(4) Use of knowledge to determine the maximum
organic vapor pressure of the hazardous waste. Documentation shall be prepared
and recorded that presents the information used as the basis for the owner's or
operator's knowledge that the maximum organic vapor pressure of the hazardous
waste is less than the maximum vapor pressure limit listed in Subsection
R315-265-1085(b)(1)(i) for the applicable tank design capacity category. An
example of information that may be used is documentation that the hazardous
waste is generated by a process for which at other locations it previously has
been determined by direct measurement that the waste maximum organic vapor
pressure is less than the maximum vapor pressure limit for the appropriate tank
design capacity category.
(d) Procedure for determining no detectable
organic emissions for the purpose of complying with Sections R315-265-1080
through R315-265-1090:
(1) The test shall be
conducted in accordance with the procedures specified in Method 21 of 40 CFR
part
60, appendix A. Each potential leak interface, for example, a location
where organic vapor leakage could occur, on the cover and associated closure
devices shall be checked. Potential leak interfaces that are associated with
covers and closure devices include, but are not limited to: The interface of
the cover and its foundation mounting; the periphery of any opening on the
cover and its associated closure device; and the sealing seat interface on a
spring-loaded pressure relief valve.
(2) The test shall be performed if the unit
contains a hazardous waste having an organic concentration representative of
the range of concentrations for the hazardous waste expected to be managed in
the unit. During the test, the cover and closure devices shall be secured in
the closed position.
(3) The
detection instrument shall meet the performance criteria of Method 21 of 40 CFR
part
60, appendix A, except the instrument response factor criteria in section
3.1.2(a) of Method 21 shall be for the average composition of the organic
constituents in the hazardous waste placed in the waste management unit, not
for each individual organic constituent.
(4) The detection instrument shall be
calibrated before use on each day of its use by the procedures specified in
Method 21 of 40 CFR part
60, appendix A.
(5) Calibration gases shall be as follows:
(i) Zero air, less than 10 ppmv hydrocarbon
in air, and
(ii) A mixture of
methane or n-hexane and air at a concentration of approximately, but less than,
10,000 ppmv methane or n-hexane.
(6) The background level shall be determined
according to the procedures in Method 21 of 40 CFR part
60, appendix
A.
(7) Each potential leak
interface shall be checked by traversing the instrument probe around the
potential leak interface as close to the interface as possible, as described in
Method 21 of 40 CFR part
60, appendix A. If the configuration of the cover or
closure device prevents a complete traverse of the interface, all accessible
portions of the interface shall be sampled. If the configuration of the closure
device prevents any sampling at the interface and the device is equipped with
an enclosed extension or horn, for example, some pressure relief devices, the
instrument probe inlet shall be placed at approximately the center of the
exhaust area to the atmosphere.
(8)
The arithmetic difference between the maximum organic concentration indicated
by the instrument and the background level shall be compared with the value of
500 ppmv except if monitoring a seal around a rotating shaft that passes
through a cover opening, in which case the comparison shall be as specified in
Subsection R315-265-1084(d)(9). If the difference is less than 500 ppmv, then
the potential leak interface is determined to operate with no detectable
organic emissions.
(9) For the
seals around a rotating shaft that passes through a cover opening, the
arithmetic difference between the maximum organic concentration indicated by
the instrument and the background level shall be compared with the value of
10,000 ppmw. If the difference is less than 10,000 ppmw, then the potential
leak interface is determined to operate with no detectable organic
emissions.