a.
Analytical
requirements. Only the analytical method(s) specified in this
paragraph, or otherwise approved by the
department, may be used to demonstrate
compliance with the requirements of 43.5(2) and 43.5(3). Measurements for pH,
temperature, turbidity, and residual
disinfectant concentrations must be
conducted by a Grade II, III or IV operator meeting the requirements of 5
67-Chapter 81, any person under the supervision of a Grade II, III or IV
operator meeting the requirements of 567-Chapter 81, or a laboratory certified
by the
department to perform analysis under 567-Chapter 83. For consecutive
public water supplies from a
surface water or groundwater under the direct
influence of
surface water system, the
disinfectant concentration analyses must
be conducted by a certified operator who meets the requirements of 567-Chapter
81. Measurements for heterotrophic plate count bacteria must be conducted by a
laboratory certified by the
department to do such analysis.
(1) Turbidity analytical methodology.
Turbidity analysis shall be conducted using the methodology in the following
table. Each turbidimeter must be calibrated at least once every 90 days with a
primary standard. The calibration of each turbidimeter used for compliance must
be verified at least once per week with a primary standard, secondary
standards, or the manufacturer's proprietary calibration confirmation device or
by a method approved by the
department. If the verification is not within plus
or minus 0.05 NTU for measurements of less than or equal to 0.5 NTU, or within
plus or minus 10 percent of measurements greater than 0.5 NTU, the turbidimeter
must be recalibrated.
|
Methodology
|
Analytical Method
|
|
EPA
|
SM
|
GLI
|
HACH
|
Other
|
|
Nephelometric5
|
180.11
|
2130B2
|
Method 23
|
FilterTrak
101334
|
|
|
Laser
Nephelometry
(online)
|
|
|
|
|
Mitchell
M52716;
Mitchell M5331
Rev. 1.210
|
|
LED Nephelometry (online)
|
|
|
|
|
Mitchell
M53317
Mitchell M5331
Rev. 1.210; AMI
Turbiwell9
|
|
LED Nephelometry (portable)
|
|
|
|
|
Orion AQ45008
|
|
360-degree Nephelometry
|
|
|
|
|
Hach Method
1025811
|
1"Methods for the Determination
of Inorganic Substances in Environmental Samples," EPA-600/R-93-100, August
1993. Available atNTIS, PB94-121811.
2
Standard Methods for the
Examination of Water and Wastewater, 18th edition, 1992, 19th edition, 1995,
20th edition, 1998, 21st edition, 2005, and 22nd edition, 2012 (any of these
editions may be used), American Public Health Association, 800 I Street, NW,
Washington, DC 20001-3710.
3GLI Method 2, "Turbidity,"
November 2, 1992, Great Lakes Instruments, Inc., 8855 North 55th Street,
Milwaukee, WI 53223.
4Hach FilterTrak Method 10133,
"Determination of Turbidity by Laser Nephelometry," January 2000, Revision 2.0,
Hach Co., P.O. Box 389, Loveland, CO 80539-0389, telephone
(800)227-4224.
5Styrene divinyl benzene beads
(e.g., AMCO-AEPA-1 or equivalent) and stabilized formazin (e.g., Hach StablCal"
or equivalent) are acceptable substitutes for formazin.
6Mitchell Method M5271, Revision
1.1. "Determination of Turbidity by Laser Nephelometry," March 5, 2009.
Available at www.nemi.gov or from Leek Mitchell, 656 Independence Valley Drive,
Grand Junction, CO 81507.
7Mitchell Method M5331, Revision
1.1. "Determination of Turbidity by LED Nephelometry," March 5, 2009. Available
at www.nemi.gov or from Leek Mitchell, 656 Independence Valley Drive, Grand
Junction, CO 81507.
8Orion Method AQ4500, Revision
1.0. "Determination of Turbidity by LED Nephelometry," May 8, 2009. Available
at www.nemi.gov or from Thermo Scientific, 166 Cummings Center, Beverly, MA
01915,www.thermo.com.
9AMI Turbiwell, "Continuous
Measurement of Turbidity Using a SWAN AMI Turbiwell Turbidimeter," August 2009.
Available at www.nemi.gov or from Markus Bernasconi, SWAN Analytische
Instrumente AG, Studbachstrasse 13, CH-8340 Hinwil, Switzerland.
10Mitchell Method M5331,
Revision 1.2. "Determination of Turbidity by LED or Laser Nephelometry,"
February 2016. Available from Leek Mitchell, 656 Independence Valley Drive,
Grand Junction, CO 81507.
11Hach Company. "Hach Method
10258 - Determination of Turbidity by 360-Degree Nephelometry," January 2016.
Available at www.hach.com.
(2) Temperature analytical methodology. The
temperature shall be determined in compliance with the methodology listed in
567-subparagraph 41.4(1)"g" (1)
(3) pH (hydrogen ion concentration)
analytical methodology. The pH shall be determined in compliance with the
methodology listed in 567-subparagraph 41.4(1)"g"
(1)
(4) Heterotrophic plate count
bacteria analytical methodology. The heterotrophic plate count bacteria
sampling and analysis shall be conducted in compliance with 567-subrule 41.2(3)
and 43.5(2)"d. " The time from sample collection to initiation
of analysis shall not exceed eight hours, and the samples must be held below 10
degrees C during transit.
(5)
Residual
disinfectant analytical methodology. The residual
disinfectant
concentrations shall be determined in compliance with one of the analytical
methods in the following table. Residual
disinfectant concentrations for free
chlorine and combined chlorine may also be measured by using DPD colorimetric
test kits. Free and total chlorine residuals may be measured continuously by
adapting a specified chlorine residual method for use with a continuous
monitoring instrument provided the chemistry, accuracy and precision remain the
same. Instruments used for continuous monitoring must be verified with a grab
sample measurement at least every seven days. The analyzer concentration must
be within plus or minus 0.1 mg/L or plus or minus 15 percent (whichever is
larger) of the grab sample measurement. If the verification is not within this
range, immediate actions must be taken to resolve the issue and another
verification must be conducted.
Disinfectant Analytical Methodology
|
Residual
|
Methodology
|
Standard
Methods1.2
|
Standard Methods
Online6
|
Other
|
|
Free chlorine
|
Amperometric Titration
|
4500-C1 D
|
4500-C1 D-00
|
D1253-034, 08, 14
|
|
DPD Ferrous Titrimetric
|
4500-C1 F
|
4500-C1 F-00
|
|
|
DPD Colorimetric
|
4500-C1 G
|
4500-C1 G-00
|
Hach Method 1026010
|
|
Syringaldazine (FACTS)
|
4500-C1 H
|
4500-C1 H-00
|
|
|
Online Chlorine Analyzer
|
|
|
EPA 334.07
|
|
Amperometric Sensor
|
|
|
ChloroSense8
|
|
Indophenol Colorimetric
|
|
|
Hach Method 10241"
|
|
Total chlorine
|
Amperometric Titration
|
4500-C1 D
|
4500-C1 D-00
|
D1253-034, 08, 14
|
|
Amperometric Titration (low-level
measurement)
|
4500-C1 E
|
4500-C1 E-00
|
|
|
DPD Ferrous Titrimetric
|
4500-C1 F
|
4500-C1 F-00
|
|
|
DPD Colorimetric
|
4500-C1 G
|
4500-C1 G-00
|
Hach Method
1026010
|
|
Iodometric Electrode
|
4500-C11
|
4500-C11-00
|
|
|
Online Chlorine Analyzer
|
|
|
EPA 334.07
|
|
Amperometric Sensor
|
|
|
ChloroSense8
|
|
Chlorine dioxide
|
Amperometric Titration
|
4500-ClO2 C
|
4500-C102 C-00
|
|
|
DPD Method
|
4500-ClO2 D
|
|
|
|
Amperometric Titration
|
4500-ClO2 E
|
4500-C102E-00
|
|
|
Amperometric Sensor
|
|
|
ChlordioX Plus9
|
|
Spectrophotometric
|
|
|
327.0, Revision
1.15
|
|
Ozone
|
Indigo method
|
45OO-O3 B3
|
45OO-O3 B-97
|
|
1
Standard Methods for the
Examination of Water and Wastewater, 18th edition, 1992, 19th edition, 1995,
20th edition, 1998, 21st edition, 2005, or 22nd edition, 2012 (any of these
editions may be used), American Public Health Association, 800 I Street, NW,
Washington, DC 20001-3710. Only the 18th, 19th, and 20th editions may be used
for chlorine dioxide Method 4500-ClO2D.
2Other analytical test
procedures are contained within Technical Notes on Drinking Water Methods,
EPA-600/R-94-173, October 1994, which is available as NTIS PB95-104766.
3
Standard Methods for the
Examination of Water and Wastewater, 18th edition (1992), 19th edition (1995),
21st edition (2005), and 22nd edition (2012) ( any edition may be used);
American Public Health Association, 800 I Street, NW, Washington, DC
20001-3710.
4Annual Book of ASTM Standards,
Vol. 11.01, 2004; ASTM International; any year containing the cited version of
the method may be used. Copies of this method may be obtained from ASTM
International, 100 Barr Harbor Drive, P.O. Box C700, West Conshohocken, PA
19428-2959.
5EPA Method 327.0, Revision 1.1,
"Determination of Chlorine Dioxide and Chlorite Ion in Drinking Water Using
Lissamine Green B and Horseradish Peroxidase with Detection by Visible
Spectrophotometry," US EPA, May 2005, EPA 815-R-05-008. Available online at
www.nemi.gov.
6
Standard Methods Online is
available at www.standardmethods.org.The year in which each method was approved
by the Standard Methods Committee is designated by the last two digits in the
method number. The methods listed are the only online versions that may be
used.
7EPA Method 334.0,
"Determination of Residual Chlorine in Drinking Water Using an On-Line Chlorine
Analyzer," August 2009. EPA815-B-09-013. Available at www.nemi.gov.
8ChloroSense, "Measurement of
Free and Total Chlorine in Drinking Water by Palintest ChloroSense," September
2009. Available at www.nemi.gov or from Palintest Ltd., 21 Kenton Lands Road,
P.O. Box 18395, Erlanger, KY 41018.
9ChlordioX Plus. "Chlorine
Dioxide and Chlorite in Drinking Water by Amperometry Using Disposable
Sensors," November 2013. Available from Palintest Ltd., Jamike Avenue (Suite
100), Erlanger, KY 41018.
10Hach Company. "Hach Method
10260 - Determination of Chlorinated Oxidants (Free and Total) in Water Using
Disposable Planar Reagent-Filled Cuvettes and Mesofluidic Channel Colorimetry,"
April 2013. Available at www.hach.com.
11Hach Company. "Hach Method
10241 - Spectophotometric Measurement of Free Chlorine in Finished Drinking
Water," November 2015, Revision 1.2. Available at
www.hach.com.
b.
Monitoring requirements. A public water system that uses a
surface water source or groundwater source under the influence of
surface water
must monitor in accordance with this paragraph.
(1) Turbidity.
1. Routine turbidity monitoring requirements.
Turbidity measurements as required by 43.5(3) must be performed on
representative samples of the system's filtered water every four hours (or more
frequently as long as measurements are recorded at equal time intervals and
detailed in the turbidity protocol) that the system serves water to the public.
A public water system may substitute continuous turbidity monitoring for grab
sample monitoring or may monitor more frequently than every four hours if it
validates the continuous measurement for accuracy on a regular basis using a
turbidity protocol approved by the department and audited for compliance during
sanitary surveys. Major elements of the protocol shall include, but are not
limited to: sample measurement location, method of calibration, calibration
frequency, calibration standards, method of verification, verification
frequency, documentation, data collection, data recording frequency, and data
reporting. For any systems using slow sand filtration or filtration treatment
other than conventional treatment, direct filtration, or diatomaceous earth
filtration, the department may reduce the sampling frequency to once per day if
it determines that less frequent monitoring is sufficient to indicate effective
filtration performance. For systems serving 500 or fewer persons, the
department may reduce the turbidity sampling frequency to once per day,
regardless of the type of filtration treatment used, if the department
determines that less frequent monitoring is sufficient to indicate effective
filtration performance. Approval shall be based upon documentation provided by
the system, acceptable to the department and pursuant to the conditions of an
operation permit.
2. Turbidity
monitoring requirements for population greater than 100,000. A supplier of
water serving a population or population equivalent of greater than 100,000
persons shall provide a continuous or rotating cycle turbidity monitoring and
recording device or take hourly grab samples to determine compliance with
43.5(3). The system must meet the requirements in 43.5(4)
"b"(1)"1," including the turbidity protocol.
3. Failure of the continuous turbidity
monitoring equipment. If there is a failure in the continuous turbidity
monitoring equipment, the system must conduct grab sampling every four hours in
lieu of continuous monitoring until the turbidimeter is repaired and back
online. A system has a maximum of five working days after failure to repair the
equipment or else the system is in violation. The system must notify the
department within 24 hours of both when the turbidimeter was taken offline and
when it was returned online.
(2) Residual
disinfectant.
1. Residual
disinfectant entering the system.
The
residual disinfectant concentration of the water entering the distribution
system shall be monitored continuously, and the lowest value recorded each day,
except that if there is a failure in the continuous monitoring
equipment, grab
sampling every four hours may be conducted in lieu of continuous monitoring,
but not to exceed five working days following the failure of
the equipment. If
acceptable to the
department, systems serving 3,300 or fewer persons may take
grab samples in lieu of providing continuous monitoring on an ongoing basis at
the frequencies prescribed below:
Residual Disinfectant Samples Required of Surface Water or
IGW PWS
|
System size (persons served)
|
Samples per day*
|
|
500 or fewer
|
1
|
|
501 to 1,000
|
2
|
|
1,001 to 2,500
|
3
|
|
2,501 to 3,300
|
4
|
*When more than one grab sample is required per day, the
day's samples cannot be taken at the same time. The sampling intervals must be
at a minimum of four-hour intervals.
If at any time the disinfectant concentration falls below
0.3 mg/L free residual or 1.5 mg/L total residual chlorine in a system using
grab sampling in lieu of continuous monitoring, the system shall take a grab
sample every four hours until the residual disinfectant concentration is equal
to or greater than 0.3 mg/L free residual or 1.5 mg/L total residual
chlorine.
2. Residual
disinfectant in the system. The residual disinfectant concentration must be
measured at least daily in the distribution system. Residual disinfectant
measurements that are required as part of the total coliform bacteria sample
collection under 567-subparagraph 41.2( 1)"c " (7) shall be
used to satisfy this requirement on the day(s) when a bacteria sample(s) is
collected. The department may allow a public water system that uses both a
groundwater source and a surface water source or a groundwater source under
direct influence of surface water to take residual disinfectant samples at
points other than the total coliform sampling points, if these points are
included as a part of the coliform sample site plan meeting the requirements of
567-paragraph 41.2(1) "c"(1)"l" and if the department
determines that such points are representative of treated (disinfected) water
quality within the distribution system. Heterotrophic plate count bacteria
(HPC) may be measured in lieu of residual disinfectant concentration, using the
analytical methods specified in 567-subparagraph
41.2(3)"e"(1). The time from sample collection to initiation
of analysis shall not exceed eight hours. HPC samples must be kept below 10
degrees C during transit to the laboratory. All HPC samples must be analyzed by
a department-certified laboratory meeting the requirements of 567-Chapter
83.