(a)
(1)
Owners or operators of closed-vent systems and control devices used to comply
with provisions of Sections
R315-264-1030
through 1036 shall comply with the provisions of Section R315-264-1033.
(2)
(i) The owner or operator of an existing
facility who cannot install a closed-vent system and control device to comply
with the provisions of Sections
R315-264-1030
through 1036 on the effective date that the facility becomes subject to the
provisions of Sections
R315-264-1030
through 1036 shall prepare an implementation schedule that includes dates by
which the closed-vent system and control device will be installed and in
operation. The controls shall be installed as soon as possible, but the
implementation schedule may allow up to 30 months after the effective date that
the facility becomes subject to Sections
R315-264-1030
through 1036 for installation and startup.
(ii) Any unit that begins operation after
December 21, 1990, and is subject to the provisions of Sections
R315-264-1030
through 1036 when operation begins, shall comply with the rules immediately,
i.e., shall have control devices installed and operating on startup of the
affected unit; the 30-month implementation schedule does not apply.
(iii) The owner or operator of any facility
in existence on the effective date of a statutory or regulatory amendment that
renders the facility subject to Sections
R315-264-1030
through 1036 shall comply with all requirements of Sections
R315-264-1030
through 1036 as soon as practicable but no later than 30 months after the
amendment's effective date. When control equipment required by Sections
R315-264-1030
through 1036 cannot be installed and begin operation by the effective date of
the amendment, the facility owner or operator shall prepare an implementation
schedule that includes the following information: Specific calendar dates for
award of contracts or issuance of purchase orders for the control equipment,
initiation of on-site installation of the control equipment, completion of the
control equipment installation, and performance of any testing to demonstrate
that the installed equipment meets the applicable standards of Sections
R315-264-1030
through 1036. The owner or operator shall enter the implementation schedule in
the operating record or in a permanent, readily available file located at the
facility.
(iv) Owners and
operators of facilities and units that become newly subject to the requirements
of Sections
R315-264-1030
through 1036 after December 8, 1997, due to an action other than those
described in Subsection R315-264-1033(a)(2)(iii) shall comply with all
applicable requirements immediately, i.e., shall have control devices installed
and operating on the date the facility or unit becomes subject to Sections
R315-264-1030
through 1036; the 30-month implementation schedule does not apply.
(b) A control device
involving vapor recovery, e.g., a condenser or adsorber, shall be designed and
operated to recover the organic vapors vented to it with an efficiency of 95
weight percent or greater unless the total organic emission limits of
Subsection
R315-264-1032(a)(1)
for all affected process vents can be attained at an efficiency less than 95
weight percent.
(c) An enclosed
combustion device, e.g., a vapor incinerator, boiler, or process heater, shall
be designed and operated to reduce the organic emissions vented to it by 95
weight percent or greater; to achieve a total organic compound concentration of
20 ppmv, expressed as the sum of the actual compounds, not carbon equivalents,
on a dry basis corrected to 3 percent oxygen; or to provide a minimum residence
time of 0.50 seconds at a minimum temperature of 760 degrees C. If a boiler or
process heater is used as the control device, then the vent stream shall be
introduced into the flame zone of the boiler or process heater.
(d)
(1) A
flare shall be designed for and operated with no visible emissions as
determined by the methods specified in Subsection R315-264-1033(e)(1), except
for periods not to exceed a total of 5 minutes during any 2 consecutive hours.
(2) A flare shall be operated with
a flame present at all times, as determined by the methods specified in
Subsection R315-264-1033(f)(2)(iii).
(3) A flare shall be used only if the net
heating value of the gas being combusted is 11.2 MJ/scm (300 Btu/scf) or
greater if the flare is steam-assisted or air-assisted; or if the net heating
value of the gas being combusted is 7.45 MJ/scm (200 Btu/scf) or greater if the
flare is nonassisted. The net heating value of the gas being combusted shall be
determined by the methods specified in Subsection R315-264-1033(e)(2).
(4)
(i) A steam-assisted or nonassisted flare
shall be designed for and operated with an exit velocity, as determined by the
methods specified in Subsection R315-264-1033(e)(3), less than 18.3 m/s (60
ft/s), except as provided in Subsections R315-264-133(d)(4)(ii) and (iii).
(ii) A steam-assisted or
nonassisted flare designed for and operated with an exit velocity, as
determined by the methods specified in Subsection R315-264-1033(e)(3), equal to
or greater than 18.3 m/s (60 ft/s) but less than 122 m/s (400 ft/s) is allowed
if the net heating value of the gas being combusted is greater than 37.3 MJ/scm
(1,000 Btu/scf).
(iii) A
steam-assisted or nonassisted flare designed for and operated with an exit
velocity, as determined by the methods specified in Subsection
R315-264-1033(e)(3), less than the velocity, Vmax, as determined by the method
specified in Subsection R315-264-1033(e)(4) and less than 122 m/s (400 ft/s) is
allowed.
(5) An
air-assisted flare shall be designed and operated with an exit velocity less
than the velocity, Vmax, as determined by the method specified in Subsection
R315-264-1033(e)(5).
(6) A flare
used to comply with Section R315-24-1033 shall be steam-assisted, air-assisted,
or nonassisted.
(e)
(1) Reference Method 22 in 40 CFR part
60
shall be used to determine the compliance of a flare with the visible emission
provisions of Sections
R315-264-1030
through 1036. The observation period is 2 hours and shall be used according to
Method 22.
(2) The net heating
value of the gas being combusted in a flare shall be calculated using the
following equation:
Ht = K times the summation product of Ci and Hi from i equals
1 to n
where:
Ht = Net heating value of the sample, MJ/scm; where the net
enthalpy per mole of offgas is based on combustion at 25 degrees C and 760 mm
Hg, but the standard temperature for determining the volume corresponding to 1
mol is 20 degrees C;
K = Constant, 1.74×10 -7
(1/ppm) (g mol/scm) (MJ/kcal) where standard temperature for (g mol/scm) is 20
degrees C;
Ci = Concentration of sample component i in ppm on a wet
basis, as measured for organics by Reference Method 18 in 40 CFR part 60 and
measured for hydrogen and carbon monoxide by ASTM D 1946-82, incorporated by
reference as specified in Section
R315-260-11; and
Hi = Net heat of combustion of sample component i, kcal/9 mol
at 25 degrees C and 760 mm Hg. The heats of combustion may be determined using
ASTM D 2382-83, incorporated by reference as specified in Section
R315-260-11, if
published values are not available or cannot be calculated.
(3) The actual exit velocity of a flare shall
be determined by dividing the volumetric flow rate, in units of standard
temperature and pressure, as determined by Reference Methods 2, 2A, 2C, or 2D
in 40 CFR part
60 as appropriate, by the unobstructed (free) cross-sectional
area of the flare tip.
(4) The
maximum allowed velocity in m/s, Vmax, for a flare complying with Subsection
R315-264-1033(d)(4)(iii) shall be determined by the following equation:
Log10(Vmax) = (HT+28.8)/31.7
where:
28.8 = Constant,
31.7 = Constant,
HT = The net heating value as determined in Subsection
R315-264-1033(e)(2).
(5)
The maximum allowed velocity in m/s, Vmax, for an air-assisted flare shall be
determined by the following equation:
Vmax = 8.706+0.7084 (HT)
where:
8.706 = Constant,
0.7084 = Constant,
HT = The net heating value as determined in Subsection
R315-264-1033(e)(2).
(f)
The owner or operator shall monitor and inspect each control device required to
comply with Section R315-264-1033 to ensure proper operation and maintenance of
the control device by implementing the following requirements:
(1) Install, calibrate, maintain, and operate
according to the manufacturer's specifications a flow indicator that provides a
record of vent stream flow from each affected process vent to the control
device at least once every hour. The flow indicator sensor shall be installed
in the vent stream at the nearest feasible point to the control device inlet
but before the point at which the vent streams are combined.
(2) Install, calibrate, maintain, and operate
according to the manufacturer's specifications a device to continuously monitor
control device operation as specified below:
(i) For a thermal vapor incinerator, a
temperature monitoring device equipped with a continuous recorder. The device
shall have an accuracy of plus or minus 1 percent of the temperature being
monitored in degrees C or +/- 0.5 degrees C, whichever is greater. The
temperature sensor shall be installed at a location in the combustion chamber
downstream of the combustion zone.
(ii) For a catalytic vapor incinerator, a
temperature monitoring device equipped with a continuous recorder. The device
shall be capable of monitoring temperature at two locations and have an
accuracy of plus or minus 1 percent of the temperature being monitored in
degrees C or +/- 0.5 degrees C, whichever is greater. One temperature sensor
shall be installed in the vent stream at the nearest feasible point to the
catalyst bed inlet and a second temperature sensor shall be installed in the
vent stream at the nearest feasible point to the catalyst bed outlet.
(iii) For a flare, a heat sensing
monitoring device equipped with a continuous recorder that indicates the
continuous ignition of the pilot flame.
(iv) For a boiler or process heater having a
design heat input capacity less than 44 MW, a temperature monitoring device
equipped with a continuous recorder. The device shall have an accuracy of plus
or minus 1 percent of the temperature being monitored in degrees C or plus or
minus 0.5 degrees C, whichever is greater. The temperature sensor shall be
installed at a location in the furnace downstream of the combustion zone.
(v) For a boiler or process heater
having a design heat input capacity greater than or equal to 44 MW, a
monitoring device equipped with a continuous recorder to measure a parameter(s)
that indicates good combustion operating practices are being used.
(vi) For a condenser, either:
(A) A monitoring device equipped with a
continuous recorder to measure the concentration level of the organic compounds
in the exhaust vent stream from the condenser, or
(B) A temperature monitoring device equipped
with a continuous recorder. The device shall be capable of monitoring
temperature with an accuracy of plus or minus 1 percent of the temperature
being monitored in degrees Celsius, or plus or minus 0.5 degrees C, whichever
is greater. The temperature sensor shall be installed at a location in the
exhaust vent stream from the condenser exit, i.e., product side.
(vii) For a carbon adsorption
system that regenerates the carbon bed directly in the control device such as a
fixed-bed carbon adsorber, either:
(A) A
monitoring device equipped with a continuous recorder to measure the
concentration level of the organic compounds in the exhaust vent stream from
the carbon bed, or
(B) A
monitoring device equipped with a continuous recorder to measure a parameter
that indicates the carbon bed is regenerated on a regular, predetermined time
cycle.
(3)
Inspect the readings from each monitoring device required by Subsections
R315-24-1033(f)(1) and (2) at least once each operating day to check control
device operation and, if necessary, immediately implement the corrective
measures necessary to ensure the control device operates in compliance with the
requirements of Section R315-264-1033.
(g) An owner or operator using a carbon
adsorption system such as a fixed-bed carbon adsorber that regenerates the
carbon bed directly onsite in the control device shall replace the existing
carbon in the control device with fresh carbon at a regular, predetermined time
interval that is no longer than the carbon service life established as a
requirement of Subsection
R315-264-1035(b)(4)(iii)(F).
(h) An owner or operator using a
carbon adsorption system such as a carbon canister that does not regenerate the
carbon bed directly onsite in the control device shall replace the existing
carbon in the control device with fresh carbon on a regular basis by using one
of the following procedures:
(1) Monitor the
concentration level of the organic compounds in the exhaust vent stream from
the carbon adsorption system on a regular schedule, and replace the existing
carbon with fresh carbon immediately when carbon breakthrough is indicated. The
monitoring frequency shall be daily or at an interval no greater than 20
percent of the time required to consume the total carbon working capacity
established as a requirement of Subsection
R315-264-1035(b)(4)(iii)(G),
whichever is longer.
(2) Replace
the existing carbon with fresh carbon at a regular, predetermined time interval
that is less than the design carbon replacement interval established as a
requirement of Subsection
R315-264-1035(b)(4)(iii)(G).
(i) An alternative
operational or process parameter may be monitored if it can be demonstrated
that another parameter will ensure that the control device is operated in
conformance with these standards and the control device's design
specifications.
(j) An owner or
operator of an affected facility seeking to comply with the provisions of Rule
R315-264 by using a control device other than a thermal vapor incinerator,
catalytic vapor incinerator, flare, boiler, process heater, condenser, or
carbon adsorption system is required to develop documentation including
sufficient information to describe the control device operation and identify
the process parameter or parameters that indicate proper operation and
maintenance of the control device.
(k) A closed-vent system shall meet either of
the following design requirements:
(1) A
closed-vent system shall be designed to operate with no detectable emissions,
as indicated by an instrument reading of less than 500 ppmv above background as
determined by the procedure in Subsection
R315-264-1034(b),
and by visual inspections; or
(2)
A closed-vent system shall be designed to operate at a pressure below
atmospheric pressure. The system shall be equipped with at least one pressure
gauge or other pressure measurement device that can be read from a readily
accessible location to verify that negative pressure is being maintained in the
closed-vent system when the control device is operating.
(l) The owner or operator shall monitor and
inspect each closed-vent system required to comply with Section R315-264-1033
to ensure proper operation and maintenance of the closed-vent system by
implementing the following requirements:
(1)
Each closed-vent system that is used to comply with Subsection
R315-264-1033(k)(1) shall be inspected and monitored in accordance with the
following requirements:
(i) An initial leak
detection monitoring of the closed-vent system shall be conducted by the owner
or operator on or before the date that the system becomes subject to Section
R315-264-1033. The owner or operator shall monitor the closed-vent system
components and connections using the procedures specified in Subsection
R315-264-1034(b)
to demonstrate that the closed-vent system operates with no detectable
emissions, as indicated by an instrument reading of less than 500 ppmv above
background.
(ii) After initial
leak detection monitoring required in Subsection R315-264-1033(l)(1)(i), the
owner or operator shall inspect and monitor the closed-vent system as follows:
(A) Closed-vent system joints, seams, or
other connections that are permanently or semi-permanently sealed, e.g., a
welded joint between two sections of hard piping or a bolted and gasketed
ducting flange, shall be visually inspected at least once per year to check for
defects that could result in air pollutant emissions. The owner or operator
shall monitor a component or connection using the procedures specified in
Subsection
R315-264-1034(b)
to demonstrate that it operates with no detectable emissions following any time
the component is repaired or replaced, e.g., a section of damaged hard piping
is replaced with new hard piping, or the connection is unsealed, e.g., a flange
is unbolted.
(B) Closed-vent
system components or connections other than those specified in Subsection
R315-264-1033(l)(1)(ii)(A) shall be monitored annually and at other times as
requested by the Director, except as provided for in Subsection
R315-264-1033(o), using the procedures specified in Subsection
R315-264-1034(b)
to demonstrate that the components or connections operate with no detectable
emissions.
(iii) In the
event that a defect or leak is detected, the owner or operator shall repair the
defect or leak in accordance with the requirements of Subsection
R315-264-1033(l)(3).
(iv) The
owner or operator shall maintain a record of the inspection and monitoring in
accordance with the requirements specified in Subsection
R315-264-1035.
(2) Each closed-vent
system that is used to comply with Subsection R315-264-1033(k)(2) shall be
inspected and monitored in accordance with the following requirements:
(i) The closed-vent system shall be visually
inspected by the owner or operator to check for defects that could result in
air pollutant emissions. Defects include, but are not limited to, visible
cracks, holes, or gaps in ductwork or piping or loose connections.
(ii) The owner or operator shall perform an
initial inspection of the closed-vent system on or before the date that the
system becomes subject to Section R315-264-1033. Thereafter, the owner or
operator shall perform the inspections at least once every year.
(iii) In the event that a defect or leak is
detected, the owner or operator shall repair the defect in accordance with the
requirements of Subsection R315-264-1033(l)(3).
(iv) The owner or operator shall maintain a
record of the inspection and monitoring in accordance with the requirements
specified in Subsection
R315-264-1035.
(3) The owner or
operator shall repair all detected defects as follows:
(i) Detectable emissions, as indicated by
visual inspection, or by an instrument reading greater than 500 ppmv above
background, shall be controlled as soon as practicable, but not later than 15
calendar days after the emission is detected, except as provided for in
Subsection R315-264-1033(l)(3)(iii).
(ii) A first attempt at repair shall be made
no later than 5 calendar days after the emission is detected.
(iii) Delay of repair of a closed-vent system
for which leaks have been detected is allowed if the repair is technically
infeasible without a process unit shutdown, or if the owner or operator
determines that emissions resulting from immediate repair would be greater than
the fugitive emissions likely to result from delay of repair. Repair of such
equipment shall be completed by the end of the next process unit shutdown.
(iv) The owner or operator shall
maintain a record of the defect repair in accordance with the requirements
specified in Section
R315-264-1035.
(m)
Closed-vent systems and control devices used to comply with provisions of
Sections R315-264-1033 through 1036 shall be operated at all times when
emissions may be vented to them.
(n) The owner or operator using a carbon
adsorption system to control air pollutant emissions shall document that all
carbon that is a hazardous waste and that is removed from the control device is
managed in one of the following manners, regardless of the average volatile
organic concentration of the carbon:
(1)
Regenerated or reactivated in a thermal treatment unit that meets one of the
following:
(i) The owner or operator of the
unit has been issued a final permit under Rule R315-270 which implements the
requirements of Sections
R315-264-600
through 603; or
(ii) The unit is
equipped with and operating air emission controls in accordance with the
applicable requirements of Sections
R315-264-1030
through 1036 and 1080 through 1090 or
40 CFR
265.1030 through 1035 and 1080 through 1090,
which are adopted by reference; or
(iii) The unit is equipped with and operating
air emission controls in accordance with a national emission standard for
hazardous air pollutants under Section R315-307-214-1, which incorporates 40
CFR part
61 or Section
R307-214-2,
which incorporates 40 CFR part
63.
(2) Incinerated in a hazardous waste
incinerator for which the owner or operator either:
(i) Has been issued a final permit under Rule
R315-270 which implements the requirements of Sections
R315-264-340
through 351; or
(ii) Has designed
and operates the incinerator in accordance with the interim status requirements
of
40 CFR
265.340 through 352, which are adopted by
reference.
(3) Burned
in a boiler or industrial furnace for which the owner or operator either:
(i) Has been issued a final permit under Rule
R315-270 which implements the requirements of Sections
R315-266-100
through 112; or
(ii) Has designed
and operates the boiler or industrial furnace in accordance with the interim
status requirements of Sections
R315-266-100
through 112.
(o) Any components of a closed-vent system
that are designated, as described in Subsection
R315-264-1035(c)(9),
as unsafe to monitor are exempt from the requirements of Subsection
R315-264-1033(l)(1)(ii)(B) if:
(1) The owner
or operator of the closed-vent system determines that the components of the
closed-vent system are unsafe to monitor because monitoring personnel would be
exposed to an immediate danger as a consequence of complying with Subsection
R315-264-1033(l)(1)(ii)(B); and
(2) The owner or operator of the closed-vent
system adheres to a written plan that requires monitoring the closed-vent
system components using the procedure specified in Subsection
R315-264-1033(l)(1)(ii)(B) as frequently as practicable during safe-to-monitor
times.