does not significantly affect
the residue by demonstrating conformance with either of the following criteria:
(1) Comparison of
waste-derived residue with
normal residue. The
waste-derived residue shall not contain appendix VIII, Rule
R315-261 constituents, toxic constituents, that could reasonably be
attributable to the
hazardous waste at concentrations significantly higher than
in residue generated without burning or processing of
hazardous waste, using
the following procedure. Toxic compounds that could reasonably be attributable
to burning or processing the
hazardous waste, constituents of concern, include
toxic constituents in the
hazardous waste, and the organic compounds listed in
appendix VIII of Rule R315-266 that may be generated as products of incomplete
combustion. For polychlorinated dibenzo-p-dioxins and polychlorinated
dibenzo-furans, analyses shall be performed to determine specific congeners and
homologues, and the results converted to 2,3,7,8-TCDD equivalent values using
the procedure specified in section 4.0 of appendix IX of Rule R315-266.
(i) Normal residue. Concentrations of toxic
constituents of concern in normal residue shall be determined based on analyses
of a minimum of 10 samples representing a minimum of 10 days of operation.
Composite samples may be used to develop a sample for analysis provided that
the compositing period does not exceed 24 hours. The upper tolerance limit, at
95% confidence with a 95% proportion of the sample distribution, of the
concentration in the normal residue shall be considered the
statistically-derived concentration in the normal residue. If changes in raw
materials or fuels reduce the statistically-derived concentrations of the toxic
constituents of concern in the normal residue, the statistically-derived
concentrations shall be revised or statistically-derived concentrations of
toxic constituents in normal residue shall be established for a new mode of
operation with the new raw material or fuel. To determine the upper tolerance
limit in the normal residue, the owner or operator shall use statistical
procedures prescribed in "Statistical Methodology for Bevill Residue
Determinations" in appendix IX of Rule R315-266.
(ii) Waste-derived residue. Waste-derived
residue shall be sampled and analyzed as often as necessary to determine
whether the residue generated during each 24-hour period has concentrations of
toxic constituents that are higher than the concentrations established for the
normal residue under Subsection R315-266-112(b)(1)(i). If so, hazardous waste
burning has significantly affected the residue and the residue shall not be
excluded from the definition of a hazardous waste. Concentrations of toxic
constituents of concern in the waste-derived residue shall be determined based
on analysis of one or more samples obtained over a 24-hour period. Multiple
samples may be analyzed, and multiple samples may be taken to form a composite
sample for analysis provided that the sampling period does not exceed 24 hours.
If more than one sample is analyzed to characterize waste-derived residues
generated over a 24-hour period, the concentration of each toxic constituent
shall be the arithmetic mean of the concentrations in the samples. No results
may be disregarded; or
(2) Comparison of
waste-derived residue
concentrations with health-based limits
(i)
Nonmetal constituents: The concentration of each nonmetal toxic constituent of
concern, specified in Subsection R315-266-112(b)(1), in the
waste-derived
residue shall not exceed the health-based level specified in appendix VII of
Rule R315-266, or the level of detection, whichever is higher. If a
health-based limit for a constituent of concern is not listed in appendix VII
of Rule R315-266, then a limit of 0.002 micrograms per kilogram or the level of
detection, which shall be determined by using appropriate analytical
procedures, whichever is higher, shall be used. The levels specified in
appendix VII of Rule R315-266, and the default level of 0.002 micrograms per
kilogram or the level of detection for constituents as identified in Note 1 of
appendix VII of Rule R315-266, are administratively stayed under the condition,
for those constituents specified in Subsection R315-266-112(b)(1), that the
owner or operator complies with alternative levels defined as the land disposal
restriction limits specified in Section
R315-268-43
for F039 nonwastewaters. In complying with those alternative levels, if an
owner or operator is unable to detect a constituent despite documenting use of
best good-faith efforts as defined by applicable guidance or standards, the
owner or operator is deemed to be in compliance for that constituent. Until new
guidance or standards are developed, the owner or operator may demonstrate such
good-faith efforts by achieving a detection limit for the constituent that does
not exceed an order of magnitude above the level provided by Section
R315-268-43
for F039 nonwastewaters. In complying with the Section
R315-268-43
F039 nonwastewater levels for polychlorinated dibenzo-p-dioxins and
polychlorinated dibenzo-furans, analyses shall be performed for total
hexachlorodibenzo-p-dioxins, total hexachlorodibenzofurans, total
pentachlorodibenzo-p-dioxins, total pentachlorodibenzofurans, total
tetrachlorodibenzo-p-dioxins, and total tetrachlorodibenzofurans.
Note to Subsection R315-266-112(b)(2)(i): The administrative
stay, under the condition that the owner or operator complies with alternative
levels defined as the land disposal restriction limits specified in Section
R315-268-43
for F039 nonwastewaters, remains in effect until further administrative action
is taken and notice is published.
(ii) Metal constituents. The concentration of
metals in an extract obtained using the Toxicity Characteristic Leaching
Procedure of Section
R315-261-24
shall not exceed the levels specified in appendix VII of Rule R315-266;
and
(iii) Sampling and analysis.
Waste-derived residue shall be sampled and analyzed as often as necessary to
determine whether the residue generated during each 24-hour period has
concentrations of toxic constituents that are higher than the health-based
levels. Concentrations of toxic constituents of concern in the waste-derived
residue shall be determined based on analysis of one or more samples obtained
over a 24-hour period. Multiple samples may be analyzed, and multiple samples
may be taken to form a composite sample for analysis provided that the sampling
period does not exceed 24 hours. If more than one sample is analyzed to
characterize waste-derived residues generated over a 24-hour period, the
concentration of each toxic constituent shall be the arithmetic mean of the
concentrations in the samples. No results may be disregarded;
and