Utah Admin. Code R315-266-104 - Hazardous Waste Burned in Boilers and Industrial Furnaces - Standards to Control Organic Emissions
(a) DRE standard
(1) General. Except as provided in Subsection
R315-266-104(a)(3),
a boiler or industrial furnace burning hazardous waste shall achieve a
destruction and removal efficiency (DRE) of 99.99% for any organic hazardous
constituents in the waste feed. To demonstrate conformance with this
requirement, 99.99% DRE shall be demonstrated during a trial burn for each
principal organic hazardous constituent (POHC) designated, under Subsection
R315-266-104(a)(2),
in its permit for each waste feed. DRE is determined for each POHC from the
following equation:
DRE = (1-Wout/Win)X100
where:
Win = Mass feed rate of one principal organic hazardous constituent (POHC) in the hazardous waste fired to the boiler or industrial furnace; and
Wout = Mass emission rate of the POHC present in stack gas before release to the atmosphere.
(2) Designation of POHCs. Principal organic
hazardous constituents (POHCs) are those compounds for which compliance with
the DRE requirements of Section
R315-266-104 shall be
demonstrated in a trial burn in conformance with procedures prescribed in
Section R315-270-66. One or more POHCs
shall be designated by the director for each waste feed to be burned. POHCs
shall be designated based on the degree of difficulty of destruction of the
organic constituents in the waste and on their concentrations or mass in the
waste feed considering the results of waste analyses submitted with part B of
the permit application. POHCs are most likely to be selected from among those
compounds listed in Rule R315-261, appendix VIII that are also present in the
normal waste feed. However, if the applicant demonstrates to the director's
satisfaction that a compound not listed in Rule R315-261, appendix VIII or not
present in the normal waste feed is a suitable indicator of compliance with the
DRE requirements of Section
R315-266-104, that compound may
be designated as a POHC. These POHCs need not be toxic or organic
compounds.
(3) Dioxin-listed waste.
A boiler or industrial furnace burning hazardous waste containing, or derived
from, EPA Hazardous Wastes Nos. F020, F021, F022, F023, F026, or F027 shall
achieve a destruction and removal efficiency (DRE) of 99.9999% for each POHC
designated, under Subsection
R315-266-104(a)(2),
in its permit. This performance shall be demonstrated on POHCs that are more
difficult to burn than tetra-, penta-, and hexachlorodibenzo-p-dioxins and
dibenzofurans. DRE is determined for each POHC from the equation in Subsection
R315-266-104(a)(1).
In addition, the owner or operator of the boiler or industrial furnace shall
notify the director of intent to burn EPA Hazardous Waste Nos. F020, F021,
F022, F023, F026, or F027.
(4)
Automatic waiver of DRE trial burn. Owners and operators of boilers operated
under the special operating requirements provided by Section
R315-266-110 are considered to
be in compliance with the DRE standard of Subsection
R315-266-104(a)(1)
and are exempt from the DRE trial burn.
(5) Low risk waste. Owners and operators of
boilers or industrial furnaces that burn hazardous waste in compliance with the
requirements of Subsection
R315-266-109(a)
are considered to be in compliance with the DRE standard of Subsection
R315-266-104(a)(1)
and are exempt from the DRE trial burn.
(b) Carbon monoxide standard.
(1) Except as provided in Subsection
R315-266-104(c),
the stack gas concentration of carbon monoxide (CO) from a boiler or industrial
furnace burning hazardous waste cannot exceed 100 ppmv on an hourly rolling
average basis, that is, over any 60 minute period, continuously corrected to 7%
oxygen, dry gas basis.
(2) CO and
oxygen shall be continuously monitored in conformance with "Performance
Specifications for Continuous Emission Monitoring of Carbon Monoxide and Oxygen
for Incinerators, Boilers, and Industrial Furnaces Burning Hazardous Waste" in
appendix IX of Rule R315-266.
(3)
Compliance with the 100 ppmv CO limit shall be demonstrated during the trial
burn, for new facilities or an interim status facility applying for a permit,
or the compliance test, for interim status facilities. To demonstrate
compliance, the highest hourly rolling average CO level during any valid run of
the trial burn or compliance test may not exceed 100 ppmv.
(c) Alternative carbon monoxide standard.
(1) The stack gas concentration of carbon
monoxide (CO) from a boiler or industrial furnace burning hazardous waste may
exceed the 100 ppmv limit except that stack gas concentrations of hydrocarbons
(HC) do not exceed 20 ppmv, except as provided by Subsection
R315-266-104(f)
for certain industrial furnaces.
(2) HC limits shall be established under
Section R315-266-104 on an hourly
rolling average basis, that is, over any 60 minute period, reported as propane,
and continuously corrected to 7% oxygen, dry gas basis.
(3) HC shall be continuously monitored in
conformance with "Performance Specifications for Continuous Emission Monitoring
of Hydrocarbons for Incinerators, Boilers, and Industrial Furnaces Burning
Hazardous Waste" in appendix IX of Rule R315-266. CO and oxygen shall be
continuously monitored in conformance with Subsection
R315-266-104(b)(2).
(4) The alternative CO standard is
established based on CO data during the trial burn, for a new facility, and the
compliance test, for an interim status facility. The alternative CO standard is
the average over each valid run of the highest hourly average CO level for each
run. The CO limit is implemented on an hourly rolling average basis, and
continuously corrected to 7% oxygen, dry gas basis.
(d) Special requirements for furnaces. Owners
and operators of industrial furnaces, for example, kilns or cupolas, that feed
hazardous waste for a purpose other than solely as an ingredient, see
Subsection R315-266-103(a)(5)(ii),
at any location other than the end where products are normally discharged and
where fuels are normally fired shall comply with the hydrocarbon limits
provided by Subsection
R315-266-104(c)
or R315-266-104(f)
irrespective of whether stack gas CO concentrations meet the 100 ppmv limit of
Subsection R315-266-104(b).
(e) Controls for dioxins and furans. Owners
and operators of boilers and industrial furnaces that are equipped with a dry
particulate matter control device that operates within the temperature range of
450-750 °F, and industrial furnaces operating under an alternative
hydrocarbon limit established under Subsection
R315-266-104(f)
shall conduct a site-specific risk assessment to demonstrate that emissions of
chlorinated dibenzo-p-dioxins and dibenzofurans do not result in an increased
lifetime cancer risk to the hypothetical maximum exposed individual (MEI)
exceeding 1 in 100,000 as follows:
(1) During
the trial burn, for new facilities or an interim status facility applying for a
permit, or compliance test, for interim status facilities, determine emission
rates of the tetra-octa congeners of chlorinated dibenzo-p-dioxins and
dibenzofurans (CDDs/CDFs) using Method 0023A, Sampling Method for
Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans Emissions
from Stationary Sources, EPA Publication SW-846, as incorporated by reference
in Section R315-260-11 or Method 23,
provided in Appendix A-7 of 40 CFR Part 60.
(2) Estimate the 2,3,7,8-TCDD toxicity
equivalence of the tetra-octa CDDs/CDFs congeners using "Procedures for
Estimating the Toxicity Equivalence of Chlorinated Dibenzo-p-Dioxin and
Dibenzofuran Congeners" in appendix IX of Rule R315-266. Multiply the emission
rates of CDD/CDF congeners with a toxicity equivalence greater than zero, see
the procedure, by the calculated toxicity equivalence factor to estimate the
equivalent emission rate of 2,3,7,8-TCDD.
(3) Conduct dispersion modeling using methods
recommended in appendix W of 40 CFR 51, "Guideline on Air Quality Models
(Revised)," 1986, and its supplements, the "Hazardous Waste Combustion Air
Quality Screening Procedure", provided in appendix IX of Rule R315-266, or in
Screening Procedures for Estimating the Air Quality Impact of Stationary
Sources, Revised, incorporated by reference in Section
R315-260-11, to predict the
maximum annual average off-site ground level concentration of 2,3,7,8-TCDD
equivalents determined under Subsection
R315-266-104(e)(2).
The maximum annual average concentration shall be used if a person resides
on-site.
(4) The ratio of the
predicted maximum annual average ground level concentration of 2,3,7,8-TCDD
equivalents to the risk-specific dose for 2,3,7,8-TCDD provided in appendix V
of Rule R315-266, 2.2x10-7, may not exceed
1.0.
(f) Monitoring CO
and HC in the by-pass duct of a cement kiln. Cement kilns may comply with the
carbon monoxide and hydrocarbon limits provided by Subsections
R315-266-104(b),
R315-266-104(c),
and R315-266-104(d)
by monitoring in the by-pass duct except that:
(1) hazardous waste is fired only into the
kiln and not at any location downstream from the kiln exit relative to the
direction of gas flow; and
(2) the
by-pass duct diverts a minimum of 10% of kiln off-gas into the duct.
(g) Use of emissions test data to
demonstrate compliance and establish operating limits. Compliance with the
requirements of Section
R315-266-104 shall be
demonstrated simultaneously by emissions testing or during separate runs under
identical operating conditions. Further, data to demonstrate compliance with
the CO and HC limits of Section
R315-266-104 or to establish
alternative CO or HC limits under Section
R315-266-104 shall be collected
during the time that DRE testing, and if applicable, CDD/CDF testing under
Subsection R315-266-104(e)
and comprehensive organic emissions testing under Subsection
R315-266-104(f)
is conducted.
(h) Enforcement. For
the purposes of permit enforcement, compliance with the operating requirements
specified in the permit, under Section
R315-266-102, shall be regarded
as compliance with Section
R315-266-104. However, evidence
that compliance with those permit conditions is insufficient to ensure
compliance with the requirements of Section
R315-266-104 may be
"information" justifying modification or revocation and re-issuance of a permit
under Section R315-270-41.
Notes
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